Table Of ContentJeenatAslam,ChandrabhanVerma,DakeshwarKumarVermaandRubyAslam(Eds.)
CarbonAllotropes
Also of Interest
Carbon-BasedSmartMaterials
ConstantinosA.Charitidis,EliasP.KoumoulosandDimitrios
A.Dragatogiannis(Eds.),
ISBN----,e-ISBN----
ChemistryofCarbonNanostructures
KlausMuellenandXinliangFeng,
ISBN----,e-ISBN----
Carbon-BasedNanotubes
RaúlHernándezSánchez,SaberMirzaeiand
EdisonArleyCastroPortillo,
ISBN----,e-ISBN----
Carbon Allotropes
Nanostructured Anti-Corrosive Materials
Edited by
Jeenat Aslam, Chandrabhan Verma,
Dakeshwar Kumar Verma and Ruby Aslam
Editors
JeenatAslam DakeshwarKumarVerma
DepartmentofChemistry DepartmentofChemistry
CollegeofScience Govt.DigvijayAutonomous
TaibahUniversity,Yanbu-30799 PostgraduateCollege
Al-Madina Chhattisgarh491441
SaudiArabia India
Email:[email protected] Email:[email protected]
ChandrabhanVerma RubyAslam
InterdisciplinaryResearchCenterforAdvanced DepartmentofAppliedChemistry
Materials FacultyofEngineeringandTechnology
KingFahdUniversityofPetroleumandMinerals AligarhMuslimUniversity
Dharan31261 Aligarh202002
SaudiArabia India
Email:[email protected] Email:[email protected]
ISBN978-3-11-078280-6
e-ISBN(PDF)978-3-11-078282-0
e-ISBN(EPUB)978-3-11-078286-8
LibraryofCongressControlNumber:2022938811
BibliographicinformationpublishedbytheDeutscheNationalbibliothek
TheDeutscheNationalbibliothekliststhispublicationintheDeutscheNationalbibliografie;
detailedbibliographicdataareavailableontheinternetathttp://dnb.dnb.de.
©2022WalterdeGruyterGmbH,Berlin/Boston
Coverimage:Gettyimages/coffeekai
Typesetting:IntegraSoftwareServicesPvt.Ltd.
Printingandbinding:CPIbooksGmbH,Leck
www.degruyter.com
About the editors
JeenatAslamDepartmentofChemistry,CollegeofScience,
TaibahUniversity,Yanbu-30799,
Al-Madina,SaudiArabia
[email protected]
JeenatAslam,Ph.D.,iscurrentlyworkingasanAssistantProfessorattheDepartmentofChemistry,
CollegeofScience,TaibahUniversity,Yanbu,Al-Madina,SaudiArabia.Herresearchmainlyfocuses
onthematerialsandcorrosion,nanotechnology,andsurfacechemistry.Dr.Jeenathaspublished
severalresearchandreviewarticlesinpeer-reviewedinternationaljournalsofACS,Wiley,Elsevier,
Springer,Taylor&Francis,BenthumScience,etc.Shehasedited2booksandhascontributed20
bookchapters.
ChandrabhanVerma
InterdisciplinaryResearchCenterforAdvancedMaterials,
KingFahdUniversityofPetroleumandMinerals,
Dhahran,31261,SaudiArabia
[email protected]
ChandrabhanVerma,worksattheInterdisciplinaryCenterforResearchinAdvancedMaterialsKing
FahdUniversityofPetroleumandMinerals(KFUPM),SaudiArabia.HeobtainedhisPhDinMaterial
Science/ChemistryattheIndianInstituteofTechnology(BanarasHinduUniversity)Varanasi,
India.HeisamemberofAmericanChemicalSociety(ACS)andservesasreviewerandeditorial
boardmemberforvariousinternationallyrecognizedofACS,RSC,Elsevier,Wiley,andSpringer
platform.Dr.VermaisAssociateEditor-in-ChiefofjournalOrganicChemistryPlus.Heistheauthor
ofseveralresearchandreviewarticlespublishedatACS,Elsevier,RSC,Wiley,Springeretc.
platforms.Hehastotalcitationofmorethan6,987withH-indexof46andi-10indexof116.
Dr.VermahaseditedeightbooksfortheACS,Elsevier,RSC,andWiley.Hereceivedseveralawards
forhisacademicachievements.
https://doi.org/10.1515/9783110782820-202
VI Abouttheeditors
DakeshwarKumarVerma
DepartmentofChemistry,
Govt.DigvijayAutonomousPostgraduateCollege,
Rajnandgaon,Chhattisgarh,INDIA491441
[email protected]
DakeshwarKumarVerma,Ph.D.,isanAssistantProfessorofChemistryattheGovt.Digvijay
AutonomousPostgraduateCollege,Rajnandgaon,Chhattisgarh,India.Hisresearchmainlyfocuseson
thepreparationanddesigningoforganiccompoundsforvariousapplicationsandgreenchemistry.Dr.
Vermaistheauthorofmorethan50researchpapers,reviewarticles,andbookchaptersinpeer-
reviewedinternationaljournalsofACS,RSC,Wiley,Elsevier,Springer,Taylor&Francis,etc.Hehas
alsoworkedasaneditor/co-editor/authoronvariousbookspublishedbyElsevier,WileyScience,and
DeGruyter.Hehastotalcitationofmorethan730withH-indexof13andi-10indexof17.Recently,two
full-timePh.D.researchscholarsareworkingunderhisguidance.Dr.VermareceivedCouncilof
ScientificandIndustrialResearchJuniorResearchFellowshipawardin2013.HealsoavailedMHRD
NationalfellowshipduringhisPh.D.in2013.
Dr.RubyAslam
DepartmentofAppliedChemistry,
AligarhMuslimUniversity,Aligarh,India.
[email protected]
RubyAslam,PhD.,isaResearchAssociateintheDepartmentofAppliedChemistry,AligarhMuslim
University,UttarPradesh,India.ShegraduatedwithanM.Sc.inChemistryatAligarhMuslim
UniversityandpresentedherM.Phil.dissertationandPh.D.thesisinAppliedChemistryatAligarh
MuslimUniversity.Shehaspublishedwidelyoncorrosioninhibitionandcorrosionprotective
coatings.
Preface
Corrosion is a high-cost and potentially hazardous issue in numerous industries.
Thepotentialuseofdiversecarbonnanoallotropesincorrosionprotection,preven-
tion, and control is a subject of rising attention. The corrosion, protection, and
control using carbon nanoallotropes is a precious reference tool for researchers
and engineers employed with nanostructure materials in various industries such
asautomotive,aerospace,petroleum,oilandgas,andchemicalengineering,along
with academics learning the exclusive protection and control offered via carbon
nanoallotropesagainstcorrosion.Thenanostructurematerials-basedprotectiveap-
proaches can suggest numerous advantages over their traditional complements;
forexample,protectionforprimaryphase,improvedcorrosioncontrol,andhigher
corrosionresistance(duetohighsurfaceareaandhighdegreeofhydrophobicity).
However, inorganic, organic, and mixed material inhibitors were used for a long
period to combat corrosion. The usage of carbon nanoallotropes as inhibitors has
expandeditsimportancebecauseofitsimprovedcorrosionefficiencyowingtothe
enlargedsurface-to-volumeratio.Thecarbonnanoallotropesaregoodcorrosionin-
hibitor because it has numerous advantages; for example, low cost, low toxicity,
easyproduction,andhighprotectionefficiency.Nanostructuresandnanostructure
materialscanassistasoutstandingcarriersforcorrosioninhibitors.Thenanostruc-
turematerials advantagesarecontrolledandactivatedreleaseof corrosioninhibi-
torstoprotectcorrosion.
This book will summarize existing research and technology on nanostructure
materials as corrosion inhibitors, obstacles in exploiting these materials, and then
outlinefutureresearchprospects.Thebookisdividedintothreeparts,andeachpart
contains numerous chapters. Part 1 “investigates the overview of carbon allotropes
andcorrosion”andcoverstopicsinChapters1to5areproperties,applications,syn-
thesis, and characterization of carbon allotropes, basics, economic adverse effects
and mitigation of corrosion, challenges and opportunities of carbon allotropes for
anticorrosive applications, and mechanism of corrosion prevention and control.
Part2,“recentadvancementsofcarbonallotropesasnanostructuredcorrosioninhi-
bitors,”studiesthetopicsinChapters6to12aregrapheneandgrapheneoxide,che-
mically modified graphene and graphene oxides, polymer composites of graphene
andgraphene oxides, carbon nanotubes (CNTs) their composites, chemicallymodi-
fiedCNTs,carbonquantumdots(CQDs),carbonnanorods(CNRs)andtheircomposi-
tesasnanostructuredcorrosioninhibitors,andrecentadvancesincarbonallotropes
nanostructuredasanticorrosivecoatings.Part3,“carbonallotropesasnanostructu-
red corrosion inhibitors: industrialization, economics, and commercialization,” co-
vers the topics in Chapters 13 to 15 are carbon allotropes nanostructured as ideal
substitutes for industrial corrosion inhibitors and recent advancements and future
proponentsofcarbonallotropes-basedmaterialsasidealsubstitutesforindustrially
https://doi.org/10.1515/9783110782820-203
VIII Preface
usefulself-healingcoatings,economics,andcommercializationofcarbonallotropes
nanostructuredcorrosioninhibitors.
Thisbook isintendedfor a verywide-ranging audienceworking inthe fields of
advancedmaterialsscience,chemistry,chemicalengineeringandtechnology,etc.It
will be aninvaluable reference sourcefor the librariesinuniversities and industrial
institutions,governmentandindependentinstitutes,individualresearchgroups,and
scientists.Overall,thisbookiswrittenfor scholarsinacademiaand industry,work-
ingcorrosionengineers,andstudentsofmaterialsscienceandappliedandengineer-
ingchemistry.Theeditorsandcontributorsarerenownedresearchers,scientists,and
trueprofessionalsfromacademiaandindustry.OnbehalfofDeGruyter,wearevery
thankfultothecontributorsofallchaptersfortheiramazingandpassionateeffortsin
themakingofthisbook.OurspecialthanksarededicatedtoDr.ChristeneSmith(Ac-
quisitions Editor), Mrs. StellaMüller (Content Editor), and the Editorial Team at De
Gruyter for their devoted supportand helpduring thisproject.In the end, all grati-
tudegoestoDeGruyterforpublishingthebook.
Editors
JeenatAslam
ChandrabhanVerma
DakeshwarKumarVerma
andRubyAslam
Contents
Abouttheeditors V
Preface VII
BhawanaJain,ReenaRawat,DanielAmoakoDarko
Chapter1
Carbonallotropes:propertiesandapplications–stateoftheart 1
AlimoradRashidi,MaryamSiratiGohari,SeyedAliRezaei
Chapter2
Carbonallotropes:synthesisandcharacterization 33
SouravKr.Saha,NamhyunKang
Chapter3
Corrosion:basics,economicadverseeffects,anditsmitigation 67
MaryamSiratiGohari,SeyedAliRezaei,AlimoradRashidi
Chapter4
Carbonallotropesforanticorrosiveapplications,challenges,
andopportunities 89
GokulRamNishad,AshwaniKumarSharma,DakeshwarKumarVerma
Chapter5
Carbonallotropes:mechanismofcorrosionpreventionandcontrol 117
OmarDagdag,RajeshHaldhar,Seong-CheolKim,ElyorBerdimurodov,
ChandrabhanVerma,EkeminiD.Akpan,EnoE.Ebenso
Chapter6
Grapheneandgrapheneoxideasnanostructuredcorrosioninhibitors 133
SanjuktaZamindar,ManilalMurmu,NareshChandraMurmu,
PriyabrataBanerjee
Chapter7
Chemicallymodifiedgrapheneandgrapheneoxidesas
corrosioninhibitors 149
X Contents
ManilalMurmu,SanjuktaZamindar,NareshChandraMurmu,
PriyabrataBanerjee
Chapter8
Polymercompositesofgrapheneandgrapheneoxidesas
corrosioninhibitors 175
SeyedAliRezaei,MaryamSiratiGohari,AlimoradRashidi
Chapter9
Carbonnanotubes(CNTs)andtheircompositesasnanostructured
corrosioninhibitors 201
AvniBerisha
Chapter10
ChemicallymodifiedCNTsascorrosioninhibitors 227
RoliJain,DanielAmoakoDarko,BhawanaJain,RuchiSharma,ReenaRawat
Chapter11
Carbonquantumdots(CQDS),carbonnanorods(CNRS),andtheircomposites
asnanostructuredcorrosioninhibitors 241
SeyyedArashHaddadi,SaeedGhaderi,
MohammadEbrahimHajiNaghiTehrani,BahramRamezanzadeh
Chapter12
Recentadvancesincarbonallotropesnanostructuredasanticorrosive
coatings 271
TaiwoW.Quadri,LukmanO.Olasunkanmi,OmololaE.Fayemi,EnoE.Ebenso
Chapter13
Industrialcorrosioninhibitors:nanostructuredcarbonallotropesas
idealsubstitutes 327
NavidHosseinabadi
Chapter14
Carbonallotropes-basedmaterialsasidealsubstitutesforindustriallyuseful
self-healingcoatings:recentadvancementsandfutureproponents 355
