Bionanotechnology: Emerging Applications of Bionanomaterials

572 Pages·2022·9.102 MB·English

by  Ahmed Barhoum, Jaison Jeevanandam, Michael K. Danquah

Bionanotechnology: Emerging Applications
of Bionanomaterials
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Micro & Nano Technologies Series
Bionanotechnology: Emerging
Applications of
Bionanomaterials
Edited by
Ahmed Barhoum
NanoStruc Research Group, Chemistry Department, Faculty of
Science, Helwan University, Ain Helwan, Cairo, Egypt; School of
Chemical Sciences, Fraunhofer Project Centre, Dublin City University,
Dublin, Ireland
Jaison Jeevanandam
CQM - Centro de Qu´ımica da Madeira, MMRG, Universidade da
Madeira, Campus da Penteada, Funchal, Portugal
Michael K. Danquah
Chemical Engineering Department, University of Tennessee,
Chattanooga, TN, United States
Elsevier
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Contents
Contributors....................................................................................................xiii
SECTION 1: Energy production and energy storage
Chapter 1: Bionanotechnology and Bionanomaterials: Emerging Applications,
Market, and Commercialization...........................................................................3
Jaison Jeevanandam, Vedarethinam Vadanasundari, Sharadwata Pan, Ahmed Barhoum and
Michael K. Danquah
1 Introduction....................................................................................................................3
2 Bionanomaterials: emerging applications.....................................................................4
3 Energy production, conversion, and storage.................................................................4
3.1 Biofuel cells............................................................................................................5
3.2 Bionanomaterial-based biodiesel............................................................................6
3.3 Metal/metal oxideebased nanocatalysts................................................................6
3.4 Carbon-based nanocatalysts....................................................................................8
3.5 Biobatteries............................................................................................................10
4 Environmental protection and improvements.............................................................12
4.1 Air filtration...........................................................................................................12
4.2 Water treatment.....................................................................................................13
4.3 Soil treatment........................................................................................................16
4.4 Plant protection.....................................................................................................17
5 Biomedical applications...............................................................................................17
5.1 Drug delivery........................................................................................................17
5.2 Wound healing......................................................................................................18
5.3 Tissue engineering applications............................................................................19
5.4 Medical implants...................................................................................................19
5.5 Biosensors.............................................................................................................20
6 Agriculture and food production industries................................................................20
6.1 Nanofertilizers.......................................................................................................21
6.2 Pesticides...............................................................................................................22
6.3 Food preservation..................................................................................................23
6.4 Food storage..........................................................................................................25
7 Other applications........................................................................................................25
7.1 Textiles..................................................................................................................26
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Contents
7.2 Paper and wood.....................................................................................................27
7.3 Automotive............................................................................................................28
8 Bionanomaterials: market growth and regulations.....................................................30
9 Commercialization of bionanomaterials......................................................................31
10 Conclusions..................................................................................................................32
References..........................................................................................................................32
Chapter 2: Smart bionanomaterials for the removal of contaminants
from wastewater..............................................................................................45
Kanakalakshmi Annamalai, Harisma Rameshbabu, Karthikeyan Mahendhran and
Murugappan Ramanathan
1 Introduction..................................................................................................................45
2 Biopolymer nanofibers in the treatment of wastewater..............................................49
3 Bioinspired nanocomposite materials in the removal of environmental
contaminants.................................................................................................................51
4 Photocatalytic applications of bionanomaterials in pollution abetment....................52
5 Nanozymes for enzymatic degradation of pollutants.................................................54
6 Biogenic nanoparticles in the removal of hazardous contaminants...........................55
7 Nanobiochar in the removal of organic and inorganic pollutants..............................58
8 Adsorption mechanism and influence of physicochemical factors............................59
9 Limitations of bionanomaterials in wastewater treatment..........................................64
10 Conclusion and future perspective..............................................................................65
References..........................................................................................................................65
SECTION 2: Environmental applications
Chapter 3: Bionanomaterials-mediated seed priming for sustainable
agricultural production.....................................................................................77
Anurag Malik, Himani Punia, Nirmal Singh and Pradeep Singh
Abbreviations.....................................................................................................................77
1 Introduction....................................................................................................................77
2 A brief history of seed priming.....................................................................................80
3 Seed priming and its application in agriculture............................................................81
4 Application of different priming approaches and priming substances........................83
4.1 Nutripriming............................................................................................................84
4.2 Hydropriming..........................................................................................................84
4.3 Solid matrix priming...............................................................................................85
4.4 Osmopriming...........................................................................................................86
4.5 Hormopriming.........................................................................................................86
4.6 Chemical priming....................................................................................................87
4.7 Biopriming...............................................................................................................87
5 Nanopriming: a novel way for seed germination and seedling growth.......................88
6 Future perspective..........................................................................................................91
7 Conclusion......................................................................................................................93
References..........................................................................................................................94
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Contents
Chapter 4: Reconnoitering bionanomaterials for mitigation of abiotic
stress in plants..............................................................................................101
Himani Punia, Jayanti Tokas, Anurag Malik and Shikha Yashveer
Abbreviations...................................................................................................................101
1 Introduction..................................................................................................................101
2 Bionanomaterials: a new frontier in plant growth and development.........................104
3 Mechanism of action of different bionanoparticles in plants.....................................105
4 Bionanomaterials: use under different stress conditions............................................109
4.1 Bionanoparticles under drought............................................................................110
4.2 Bionanoparticles under salinity............................................................................115
5 Environmental and safety issues.................................................................................118
6 Future perspective........................................................................................................119
7 Conclusion....................................................................................................................120
References........................................................................................................................120
SECTION 3: Biomedical applications
Chapter 5: Emerging applications of bionanomaterials in medicine
and drug delivery...........................................................................................129
Dalapathi Gugulothu and Dharmendra Kumar Khatri
Abbreviations...................................................................................................................129
1 Introduction..................................................................................................................130
2 Inorganic bionanomaterials..........................................................................................132
2.1 Metal nanoparticles and metal oxide nanoparticles.............................................132
2.2 Other inorganic bionanomaterials........................................................................133
2.3 Carbon bionanomaterials......................................................................................134
2.4 Polymeric bionanomaterials..................................................................................142
2.5 Lipid bionanomaterials.........................................................................................158
2.6 Others....................................................................................................................168
3 Conclusions and future prospects................................................................................175
Acknowledgments............................................................................................................176
References........................................................................................................................176
Chapter 6: Polymer-based bionanomaterials for biomedical applications..............187
Tabassum Khan and Akshita Chauhan
1 Introduction..................................................................................................................187
2 Types of polymeric nanomaterials..............................................................................189
2.1 Natural polymeric nanomaterials.........................................................................189
2.2 Engineered polymeric nanomaterials...................................................................190
2.3 Biosynthesized polymeric nanomaterials.............................................................191
2.4 Chemosynthesis polymeric nanomaterials...........................................................193
3 Biofunctionalized nanocellulosic materials.................................................................194
3.1 Nanocellulose-based biodegradable polymers.....................................................194
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Contents
3.2 Nanocellulose-based thermoplastic polymers......................................................197
3.3 Porous nanocellulose composites.........................................................................198
4 Bioinspired polymeric nanocomposites.......................................................................200
4.1 Polymeric nanocomposite hydrogels....................................................................200
4.2 Bioactive silicate-based nanocomposites.............................................................201
4.3 Bioinspired hydroxyapatite nanocomposites........................................................202
4.4 Bioinspired Rosette Nanotube composites...........................................................202
4.5 Graphene-enhanced polymeric nanocomposites..................................................202
4.6 Polymeric nanocomposites loaded with metallic nanoparticles..........................203
4.7 Mechanically stiff interpenetrating networks.......................................................203
4.8 Spatially controlled hydrogel nanocomposites....................................................204
5 Biomedical applications...............................................................................................204
5.1 Dental and biomedical implants...........................................................................205
5.2 Targeted drug delivery..........................................................................................206
5.3 Bionanomaterials for therapy of defective joints and bones...............................207
5.4 Bone tissue engineering........................................................................................208
5.5 Biosensor platforms..............................................................................................209
5.6 Vaccine development............................................................................................210
5.7 Fluorescent polymeric nanovehicles....................................................................211
5.8 Fluorescent bioimaging.........................................................................................211
5.9 Stem cell imaging.................................................................................................212
6 Future perspective........................................................................................................213
7 Conclusion....................................................................................................................213
References........................................................................................................................214
Chapter 7: Photocatalytic metal bionanocomposites for biomedical
applications...................................................................................................227
Selma Hamimed and Abdelwaheb Chatti
1 Introduction..................................................................................................................227
2 Overview of bionanocomposites.................................................................................229
3 Photocatalytic activity of metal bionanocomposites..................................................231
3.1 TiO bionanocomposites.......................................................................................231
2
3.2 Mixed metal oxide bionanocomposites................................................................232
3.3 Polymeremetal and graphene metal bionanocomposites....................................235
3.4 Other metal bionanocomposites...........................................................................236
4 Biomedical applications of photocatalytic metal bionanocomposites.......................236
4.1 Drug delivery........................................................................................................237
4.2 Biosensor and bioimaging....................................................................................240
4.3 Bone and cartilage tissues engineering................................................................241
4.4 Antimicrobial and antioxidant agents..................................................................245
4.5 Other biomedical applications..............................................................................248
5 Conclusion....................................................................................................................250
References........................................................................................................................250
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Contents
Chapter 8: Bionanomaterials for wound healing applications..............................259
Itisha Chummun, Honita Ramphul, Dhanjay Jhurry and Archana Bhaw-Luximon
List of abbreviations........................................................................................................259
1 Introduction..................................................................................................................260
2 Challenges of skin and skeletal tissue wounds...........................................................262
2.1 Burns.....................................................................................................................263
2.2 Diabetic wounds....................................................................................................264
2.3 Bone fracture.........................................................................................................266
2.4 Ligament and tendon damage..............................................................................267
3 Nanobiomaterials used as scaffolds for skin and skeletal tissue regeneration..........269
3.1 Cellulose-based scaffolds......................................................................................269
3.2 Seaweeds polysaccharide-based scaffolds............................................................274
3.3 Sucrose-based scaffolds........................................................................................279
4 Peptide hydrogels for wound healing..........................................................................280
5 Nanobiomaterials and natural molecules to enhance biological performance..........284
6 Commercially available wound healing scaffolds......................................................286
7 Conclusion and future perspectives in wound tissue regeneration............................291
References........................................................................................................................292
Further reading................................................................................................................304
Chapter 9: Polymeric bionanomaterials for diabetes applications........................305
Aristeidis Papagiannopoulos, Evdokia Stefanopoulou, Eleni Vlassi and Stergios Pispas
1 Introduction..................................................................................................................305
2 Delivery of antidiabetic medicines using nanoparticles.............................................307
2.1 Chitosan-based nanoparticles................................................................................307
2.2 Nanoparticles of other naturally occurring biopolymers.....................................313
2.3 Nanoparticles of synthetic biopolymers...............................................................316
3 Hydrogels employed for the treatment of diabetes....................................................318
4 Future prospects...........................................................................................................325
5 Conclusion....................................................................................................................326
References........................................................................................................................327
SECTION 4: Constructions and other applications
Chapter 10: Nanohydrogels for targeted drug delivery systems...........................333
Lalita Devi, Hitesh Chopra and Punam Gaba
1 Introduction..................................................................................................................333
2 Structure of nanoparticleehydrogel composites.........................................................334
2.1 Nano- and microgel composites...........................................................................334
2.2 Macroscopic hydrogel composites.......................................................................334
3 Synthesis method.........................................................................................................335
3.1 Bulk polymerization..............................................................................................336
3.2 Solution polymerization........................................................................................336
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