Alloys and Compounds of d-Elements with Main Group Elements. Part 2

306 Pages·1988·4.26 MB·English

by  Y. Nakamura (auth.)

.feR .p 117 1.4.5.1 d3 - puorg B4 :stnemele noitcudortni 1
1 citengaM seitreporp fo ,d3 ,d4 dna d5 elements, syolla dna
compounds
1.1 d3 stnemele
2.1 syollA neewteb d3 stnemele
3.1 d4 dna d5 ,stnemele syolla dna sdnuopmoc
4.1 syollA dna sdnuopmoc fo d3 stnemele dna d4 ro d5 stnemele
eeS emulovbuS a91/111
5.1 syollA and compounds of 3d stnemele htiw niam group stnemele
1.5.1 d3 stnemele dna ,uC gA ro uA
2.5.1 d3 stnemele dna ,eB ,gM nZ ro gH
3.5.1 d3 stnemele dna ,B ,lA ,aG nI ro lT
eeS emulovbuS l/III b9
45.1 d3 stnemele dna ,C ,iS ,eG nS or bP
1.4.5.1 noitcudortnI
)a esahP margaid dna latsyrc erutcurts
seitilibuloS dna cillatemretni ni’sdnuopmoc yranib smetsys era nwohs ni elbaT .1 ehT seitilibulos fo puorg B4
stnemele ni d3 stnemele era llams dna yeht form ynam sdnik fo cillatemretni .sdnuopmoc lareveS latsyrc
serutcurts er& nwohs sa :serugif g,Xl,M ni .giF ,03 ),,OD(X,M ni .giF ,94 ,OD(X,M J ni .giF ,66 )61C(,XM ni
.giF ,951 ,X,M )lardehobmohr( ni .giF 561 dna )53B(XM ni .giF .071 ,yllanoitiddA eerht latsyrc ,serutcurts
,),8D(,X,M ),OD(X,M dna ,),8B(,X,M era nwohs ,woleb gnitacidni hcae cihpargollatsyrc .etis
X3M 3on
,X,M B82
l M smota no 6g setis 0 M smota no C setis 0 smotaM no a2 setis
63 M smota no Ld setis @ M smota no O/B setis @ X/M smota no setisc2
0 X smota no 6g setis o X smota no A setis 0 X/M smota no 2d setis
nietsm;bB-&dnaL arumakaN
weN seireS III/19c,
elbaT .1 ytilibuloS stimil dna cillatemretni sdnuopmoc yranibfo syolla neewteb d3 dna puorg B4 .stnemele eeS 85[ ]h fi ton esiwrehto .deton ehT latsyrc erutcurts fo
hcae cillatemretni dnuopmoc si nevig ni .sesehtnerap :xeh ,lanogaxeh :ohtro ,cibmohrohtro :onom ,cinilconom :rtet ,lanogartet :buc ,cibuc :bmohr .lardehobmohr
iT V rC nM eF oc iN
C ytilibulos ytilibulos elbulosni ytilibulos tsomla elbulosni tsomla elbulosni ytilibulos
C ni iT-r %54.0 niC V %1 C ni nM-rc %2 C ni eF-r C ni oC C ni iN %2
)1B(CiT 561 el )48D(6C32rC UD(G,,nM ,OD(GF ,I ,OD(C,oC ,I Ni$W, J
)buc(C,iT 96[ ]s V*Wd )xehXdrC )xeh(,C,,nM )pch(C,eF-c TH )ohtro(C,oC 96C 1~
)ICaN(CV MD(GrC 56C el )pch(C,eF 56[ ]e
)ICaN(CrC )ohtro(,C,nM )onom(,C,eF
96C 1~
)onom(,C,nM
iS ytilibulos ytilibulos ytilibulos ytilibulos ytilibulos ytilibulos ytilibulos
iS ni iT-a %1.1 iS ni V %5.4< iS ni rC %31 iS ni nM-cs %6 iS ni eF-r %62 iS ni %61~210C-E iS ni iN %01
rtet(iS,iT )P,iT )SlA(iS,V rC ni iS %8.1 96C 1~ ),OD(iS,eF )32C(iS,oC ),IL(iS,iN 76[ ]p
961 1~ VsW%) )5lA(iS,rC )xeh(iS,nM 96[ ]s ),8D(,iS,eF (iSoC )02B )bmohrJiSsiN
),8D(,iS,iT )04C(,iSV )rtet(,iS,rC )?(,iS,nM 96[ ]s )02B(iSeF )lC(2iSoC )32C(iS,iN 76[ ]p
)72B(iSiT )02B(iSrC ),OD(iS,nM )rtet(,iSeF 96[ ]s )ohtro(,iS,iN
)45CJiSiT )04CJiSrC ),8D(,iS,nM )02B(iSiN
)02B(iSnM )lC(,SiN
,,iS,,nM ]s96[
eG ytilibulos tsomla elbulosni elbulosni ytilibulos ytilibulos ytilibulos ytilibulos
eG ni iT-a %8 )SlA(eG,V )SlA(eG,rC eG ni nM-u %2 eG ni eF-r %9 eG ni OC-E %01 eG ni iN %21
)45C(,eGiT UP,eG,V )?(,eG,rC &OD(eG,nM ),IL(eG,eF )8B(eG,oC JIL(eG,iN
),8D(,eG,iT 56C le )lT(,eG,rC ),8B(,eG,nM (eGeF )53B 76[ ]p )onom(eGoC ]p76[ )xeh(eGziN
)72B(eGiT 56[ ]e ,V )ohtro(,eG, ,rC )ohtro(,eG, )8W3eGsnM )6lCJeGeF )tcb(,eG,oC 56[ ]e )13B(eGiN
)rtet(zeGV )02B(eGrC 96[ ]s )?(,eG,nM )ohtro(zeGoC
nS ytilibulos ytilibulos elbulosni elbulosni elbulosni tsomla elbulosni tsomla elbulosni
nS ni iT-a %5.9 nS ni V %01 )xelpmoc(,nS$rC ),,OWS,nM ),,OO&e~ nS ni oC-c WSnW3)
56C le 561 el 96[ ]s ),8B(nQtM MWn$eF CGWB8,) 761 IP 56C le
)9W(nS3iT )SlA(nS,V )6lC(nSnM )bmohr(znS,eF )53B(nSoC )8B(znS,iN
)8B(nSziT )53B(nSeF znSoC )53B(,nS,iN
WU3nGT )61C(znSeF
)ohtro(,nS,iT ]s96[
bP elbulbsni elbulosni elbulosni elbulosni elbulosni elbulosni elbulosni
),,OD(bP,iT )SlA(bP,V ]s96[
bP,iT
.feR .p 117 2.4.5.1 ,iT V - puorg B4 stnemele 3
)b citengaM seitreporp
ehT citengam seitreporp fo syolla neewteb d3 stnemele dna puorg B4 stnemele evah neeb deiduts yllaicepse
rof nM dna eF cillatemretni .sdnuopmoc yehT wohs tsomla lla gnorts citengam roivaheb hcus sa
,msitengamorref ,msitengamirref msitengamorrefitna dna .msitengamileh ynaM iT dna V cillatemretni
sdnuopmoc htiw puorg B4 stnemele era srotcudnocrepus saerehw most fo ,rC oC dna iN cillatemretni
sdnuopmoc era .stengamarap
)c stnemegnarrA fo slairetam
yraniB syolla dna sdnuopmoc era degnarra ni eht redro fo gnisaercni cimota rebmun fo eht d3 .tnemele nI eht
gniwollof snoitcesbus fo ,iT ,V ,rC ,nM ,eF ,oC dna iN syolla dna sdnuopmoc eht ecneuqes fo eht trapretnuoc
stnemele si ,C ,iS ,eG ,nS dna .bP
ehT yranret syolla dna sdnuopmoc ,era ni ,elpicnirp decalp retfa eht yranib syolla fo rieht .stneutitsnoc ehT
yranret sdnuopmoc ,X’MM erehw M dna ’M etoned tnereffid d3 stnemele dna X stneserper eno fo eht
trapretnuoc ,stnemele si decalp ni noitcesbus .7.4.5.1
2.4.5.1 Ti dna V syolla dna sdnuopmoc
tsoM fo eht iT dna V sdnuopmoc era .citengamarap ecniS X,V sdnuopmoc emoceb srotcudnocrepus ta
ylevitaler hgih ,serutarepmet rieht lacisyhp seitreporp gnidulcni citengam seitreporp evah neeb deiduts ni .liated
yevruS
noitisopmoC x seitreporP erugiF elbaT
,iT ,$- 984.0..*523.0 )x(,x 1
ciT )T(,L 2 2
,iS,iT 2
,iSiT ,iSiT x&T) 3 2
IV ,cx- ..593.0 854.Oe )xsnx 1
,iT C,V,- l...O )x(,x 4
)H(gx 5
v,c
3
iS,V 6 3
7
eG,V 6 3
7
nS,V 6 3
,iSV 3
IV( iS3J.rCx- 8
,iS,V ,o$- ,9 01
,iS,V ,eGx- 21,II
,sO,eG,V x- 31
elbaT .2 citengaM dna detaler seitreporp fo ciT 95[ B ,]I ,iS,iT SS[ R ,]I iSiT dna ,iSiT 07[ R .J-1
ciT ,iS,iT iSiT ,iSiT
cihpargollatsyrC cibuc lanogaxeh cibmohrohtro cibmohrohtro
erutcurts )ICaN(lB ),iS,nM(,8D )BeF(72B 45c
a 1AC 923.4 364.7 35.6 32.8
b 1AC 46.3 77.4
c 1AC 561.5 00.5 85.8
msitengaM ’ arap arap arap arap
gx 6e01[ ]g/”mc 01.0 ta TR 05.2 ta TR 02.0 ta TR 91.1 ta TR
- ..-..
n~etsnr0imoanaL arumakaN
weN seireS III/19c
.feR .p 117 2.4.5.1 ,iT V - puorg B4 stnemele 3
)b citengaM seitreporp
ehT citengam seitreporp fo syolla neewteb d3 stnemele dna puorg B4 stnemele evah neeb deiduts yllaicepse
rof nM dna eF cillatemretni .sdnuopmoc yehT wohs tsomla lla gnorts citengam roivaheb hcus sa
,msitengamorref ,msitengamirref msitengamorrefitna dna .msitengamileh ynaM iT dna V cillatemretni
sdnuopmoc htiw puorg B4 stnemele era srotcudnocrepus saerehw most fo ,rC oC dna iN cillatemretni
sdnuopmoc era .stengamarap
)c stnemegnarrA fo slairetam
yraniB syolla dna sdnuopmoc era degnarra ni eht redro fo gnisaercni cimota rebmun fo eht d3 .tnemele nI eht
gniwollof snoitcesbus fo ,iT ,V ,rC ,nM ,eF ,oC dna iN syolla dna sdnuopmoc eht ecneuqes fo eht trapretnuoc
stnemele si ,C ,iS ,eG ,nS dna .bP
ehT yranret syolla dna sdnuopmoc ,era ni ,elpicnirp decalp retfa eht yranib syolla fo rieht .stneutitsnoc ehT
yranret sdnuopmoc ,X’MM erehw M dna ’M etoned tnereffid d3 stnemele dna X stneserper eno fo eht
trapretnuoc ,stnemele si decalp ni noitcesbus .7.4.5.1
2.4.5.1 Ti dna V syolla dna sdnuopmoc
tsoM fo eht iT dna V sdnuopmoc era .citengamarap ecniS X,V sdnuopmoc emoceb srotcudnocrepus ta
ylevitaler hgih ,serutarepmet rieht lacisyhp seitreporp gnidulcni citengam seitreporp evah neeb deiduts ni .liated
yevruS
noitisopmoC x seitreporP erugiF elbaT
,iT ,$- 984.0..*523.0 )x(,x 1
ciT )T(,L 2 2
,iS,iT 2
,iSiT ,iSiT x&T) 3 2
IV ,cx- ..593.0 854.Oe )xsnx 1
,iT C,V,- l...O )x(,x 4
)H(gx 5
v,c
3
iS,V 6 3
7
eG,V 6 3
7
nS,V 6 3
,iSV 3
IV( iS3J.rCx- 8
,iS,V ,o$- ,9 01
,iS,V ,eGx- 21,II
,sO,eG,V x- 31
elbaT .2 citengaM dna detaler seitreporp fo ciT 95[ B ,]I ,iS,iT SS[ R ,]I iSiT dna ,iSiT 07[ R .J-1
ciT ,iS,iT iSiT ,iSiT
cihpargollatsyrC cibuc lanogaxeh cibmohrohtro cibmohrohtro
erutcurts )ICaN(lB ),iS,nM(,8D )BeF(72B 45c
a 1AC 923.4 364.7 35.6 32.8
b 1AC 46.3 77.4
c 1AC 561.5 00.5 85.8
msitengaM ’ arap arap arap arap
gx 6e01[ ]g/”mc 01.0 ta TR 05.2 ta TR 02.0 ta TR 91.1 ta TR
- ..-..
n~etsnr0imoanaL arumakaN
weN seireS III/19c
4 2.4.5.1 ,iT V - puorg B4 stnemele .feR[ .p 17
elbar .3 citengaM dna detaler seitreporp fo C,V CO7[ ,11 iS,V 16[ C ,11 ,iSV SS[ R ,11 eG,V dna nS,V
16[ C .J-1 nI noitcennoc htiw gnitcudnocrepus ,seitreporp eht thginK stfihs fo X,V evah neeb derusaem
16[ C .11
c,v iS,V ,iSV eG,V nS,V
cihpargollatsyrC lanogaxeh cibuc lanogaxeh cibuc cibuc
erutcurts LW%N) lA W-w) ),iSrC(O4C lA W-W lA W-w)
a PI 78.2 127.4 175.4 967.4 49.4
c [Al 55.4 273.6
0lc 95.1 493.1
msitengaM arap arap arap arap arap
xg lW6 cm3/gl 55.1 ta TR 6.5 ta TR 35.1 ta TR 3.4 ta TR 4.3 ta TR
T, 1‘ WI 1.71 0.6 l<
)‘ gnitcudnocrepuS noitisnart .erutarepmet
021 5.1
6w. “o-3”
@I&
lom -T
100 0.9
I
”H
80
0.6
I
’H 06
3.0
04
0 002 004 006 008 1000 K 1200
-l
02
.giF .3 ,iSiT .,iSiT erutarepmeT ecnedneped fo eht
citengam ytilibitpecsus 07[ R .11
0
03 53 04 54 %ta 05
-c
03
.giF .1 ,iT ,,$- ,V .,$- noitartnecnoC ecnedneped s-04
fo eht erutarepmet-moor citengam ytilibitpecsus 06[ B .11 Jrg
ehT syolla erew dezinegomoh ta C°0022 rof .h01 lom
1 I I I I
0 002 004 006 008 1000 1200 K 1400 0 2.0 4.0 6.0 8.0 1.0
l- XT -x cv
.giF .2 .CIT erutarepmeT ecnedneped fo eht citengam .giF .4 .C,V,-,iT noitisopmoC ecnedneped fo eht
ytilibitpecsus .]lL97[ ehT ncmiccps saw delaenna ta erutarepmet-moor citengam ytilibitpecsus 95[ B .11
.K0881 ehT ytilibitpecsus saw derusaem ta .eOk21
arumakaN nkm6B&dnaL
WN ceireS ~91’111
.feR .p 117 2.4.5.1 ,iT V - puorg B4 stnemele
0.4 I 9
.1O-6 TR 6.oVuiT C 6Tll. -. _
3mc 3 ,V,\ iS
7
h
0 0.4 0.8 1.2 1.6 do-“OF 2.0
l-H -
.giF 5. ,C4,0V,,,iT .!&V,,,,iT citengaM dleif -neped
ecned of eht erutarepmet-moor citengam ytilibitpecsus
[59 B 11.
I I I I I I I
0 50 100 150 200 250 K 300
-T
.giF 6. ,iS,V ,eG,V .nS,V erutarepmeT ecnedneped of
eht citengam ytilibitpecsus [61 C I].
4 6 8 Wcm3/g 12 6
xg -
5
.giF I. ,iS,V .eG,V thginK shift of V15 .sv cx For iS3V
eht thginK shift of iS“ sah neeb derusaem ta eno
I
erutarepmet [61 C I]. 4$
3
2
1
I I I I
0 50 100 150 200 250 K 300
-T
.giF 8. ,V( .i$JrC,- erutarepmeT ecnedneped of eht
citengam .ytilibitpecsus :0=x elgnis esahp (f) dna V-u
setatipicerp (2) [79 H 11.
arumakaN
6 2.451 ,iT V - puorg B4 stnemele .feR[ .p 17
51
’rcl. % V Si _ oC
-cm3 3 xIl x 1 ( ”“ 1
lom
8
6
0 05 001 051 002 052 K 003
-l
.giF .9 ,i$V .,oC,- crutarcpmeT ecnedneped fo eht
citengam ytilibitpecsus 18[ A .]I
021
’-oJ
-cm3
lom
5.11
0 05 001 051 002 052 K 003
0.01 -I
.giF .01 ,i$V .,o$- erutarepmeT ecnedneped fo eht
thginK tfihs fo V’5 )a( dna iSg2 )b( 18[ A .11
.giF .11 .,eG,-,iS,V erutarepmeT ccnedncpcd fo eht
citengam ytilibitpecsus 37[ 0 .J-1
arumakaN
.feR .p 117 3.4.5.1 rC - puorg B4 stnemele 7
0.63
%
50
0.62
6w
- 3mc
0.61 9
0.60
4.0
I
k 0.59
I 3.5
”x
058
3.0
0.57
2.5
0.56
0.55 2.0
0 0.2 0.4 0.6 0.8 1.0 0 50 100 150 200 250 K 300
iS3V -x eG3V l-
.giF .21 ,iSaV . . ..eG.. smrehtosI fo eht thginK tfihs .giF .31 ,sO,eG,V .X- erutarepmeT ecnedneped fo eht
fo v15 37[ 0 .]I citengam ytilibitpecsus 87[ P .]I
3.4.5.1 rC syolla dna sdnuopmoc
hcir-rC syolla yllaicepse htiw iS dna eG evah ylevisnetxe neeb detagitsevni ni noitcennoc htiw nips ytisned
sevaw (SDW) woleb rieht 1e&N .serutarepmet rC sdnuopmoc htiw iS dna eG deiduts os raf wohs msitengamarap
tpecxe rof .,,eG,,rC
yevruS
noitisopmoC x seitreporP erugiF elbaT
,rC ,iS,- 0.0046, 2210.0 )T(gx 41
..0 7630.Oe )0 51
20.0~~~900.0 W(T) 61
60.0...0 )X(P 71
4720.0...0 Q(x) 81
T-x citengam esahp margaid 91
410.0 Tp citengam esahp margaid 02
..742.0 452.0- 12 4
iSrC gE 22 4
,iS.-,rC 220.0*~~5300.0 )TC@ 32
210.0~~~200.0 )U/lA 42
30.0..*0 ,)x(p Q(x) ,52 62
T-x citengam esahp margaid 72
eG,rC )T(gx 82 4
,eGsrC )T(gx 82 4
eGrC ix 76‘ 92 4
91eGllrC latsyrc erutcurts 03 4
,x OC‘ )T(a 13
nietsnriiB-&dnaL arumakaN
weN seireS .c9ljIlI
.feR .p 117 3.4.5.1 rC - puorg B4 stnemele 7
0.63
%
50
0.62
6w
- 3mc
0.61 9
0.60
4.0
I
k 0.59
I 3.5
”x
058
3.0
0.57
2.5
0.56
0.55 2.0
0 0.2 0.4 0.6 0.8 1.0 0 50 100 150 200 250 K 300
iS3V -x eG3V l-
.giF .21 ,iSaV . . ..eG.. smrehtosI fo eht thginK tfihs .giF .31 ,sO,eG,V .X- erutarepmeT ecnedneped fo eht
fo v15 37[ 0 .]I citengam ytilibitpecsus 87[ P .]I
3.4.5.1 rC syolla dna sdnuopmoc
hcir-rC syolla yllaicepse htiw iS dna eG evah ylevisnetxe neeb detagitsevni ni noitcennoc htiw nips ytisned
sevaw (SDW) woleb rieht 1e&N .serutarepmet rC sdnuopmoc htiw iS dna eG deiduts os raf wohs msitengamarap
tpecxe rof .,,eG,,rC
yevruS
noitisopmoC x seitreporP erugiF elbaT
,rC ,iS,- 0.0046, 2210.0 )T(gx 41
..0 7630.Oe )0 51
20.0~~~900.0 W(T) 61
60.0...0 )X(P 71
4720.0...0 Q(x) 81
T-x citengam esahp margaid 91
410.0 Tp citengam esahp margaid 02
..742.0 452.0- 12 4
iSrC gE 22 4
,iS.-,rC 220.0*~~5300.0 )TC@ 32
210.0~~~200.0 )U/lA 42
30.0..*0 ,)x(p Q(x) ,52 62
T-x citengam esahp margaid 72
eG,rC )T(gx 82 4
,eGsrC )T(gx 82 4
eGrC ix 76‘ 92 4
91eGllrC latsyrc erutcurts 03 4
,x OC‘ )T(a 13
nietsnriiB-&dnaL arumakaN
weN seireS .c9ljIlI
8 3.4.5.1 rC - puorg B4 stnemele .feR[ .p 17
elbaT .4 citengaM dna detaler seitreporp fo iS,rC 97[ M ,11 iSrC 27[ W ,]I ,eG,rC ,,eG,rC ,eGrC ,rC ,,eGI
08[ K .11
iS,rC iSrC eG,rC ,eG,rC eGrC ,rC Jkg
cihpargollatsyrC cibuc cibuc cibuc lanogartet cibuc lanogartet
erutcurts lA W-W )iSeF(OZB lA 5@-W) W,,(W&) )iSeF(OZB g%llnM
4sahp-lT(
a [Al 4.555 4.629 4.631 9.410 4.196 5.79
c [Al 4.783 51.87
ad 0.508 8.96
msitengaM arap tnatsnoc tnatsnoc tnatsnoc arap orref
arap arap arap
T, IKC 19
IKCQ 170
C~P lrKhC 10.3 31.2
330
6-lx
3
1 $
$20
315
4
3.10 .giF .41 .iS-rC erutarepmeT ecnedneped fo eht -gam
5 0 citcn ytilibitpecsus 28[ B .11
60
mc@
4
.giF .51 .iS-rC lacirtcelE -vitsiser
0 40 80 120 160 200 250 280 K 320 yti nccwtcb 4 dna K023 A76[ .]I
-l
arumakaN nietsmGB-hodnaL
weN seireS ~91’111