Advances in the environmental biogeochemistry of manganese oxides

208 Pages·2015·5.101 MB·English

by  Spyri, Johanna

Advances in the Environmental
Biogeochemistry of Manganese
Oxides
In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
1197
ACS SYMPOSIUM SERIES
Advances in the Environmental
Biogeochemistry of Manganese
Oxides
Xionghan Feng, Editor
HuazhongAgriculturalUniversity,Wuhan,China
Wei Li, Editor
Nanjing University, Nanjing, China
Mengqiang Zhu, Editor
UniversityofWyoming,Laramie,Wyoming,UnitedStates
Donald L. Sparks, Editor
UniversityofDelaware,Newark,Delaware,UnitedStates
Sponsored by the
ACS Division of Geochemistry
AmericanChemicalSociety,Washington,DC
DistributedinprintbyOxfordUniversityPress
In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
LibraryofCongressCataloging-in-PublicationData
Names:Feng,Xionghan,editor.|AmericanChemicalSociety.Divisionof
Geochemistry.
Title:Advancesintheenvironmentalbiogeochemistryofmanganeseoxides/
XionghanFeng,editor,HuazhongAgriculturalUniversity,Wuhan,China[and
threeothers];sponsoredbytheACSDivisionofGeochemistry.
Description:Washington,DC:AmericanChemicalSociety,[2015]|[Oxford]:
DistributedinprintbyOxfordUniversityPress|Series:ACSsymposium
series:1197|Includesbibliographicalreferencesandindex.
Identifiers:LCCN2015039378|ISBN9780841230965|ISBN9780841230958
Subjects:LCSH:Manganeseoxides.|Manganese--Environmentalaspects.|
Biogeochemistry.
Classification:LCCTN490.M3A272015|DDC577/.14--dc23LCrecordavailableat
http://lccn.loc.gov/2015039378
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In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
Foreword
The ACS Symposium Series was first published in 1974 to provide a
mechanism for publishing symposia quickly in book form. The purpose of
the series is to publish timely, comprehensive books developed from the ACS
sponsoredsymposiabasedoncurrentscientificresearch. Occasionally,booksare
developed from symposia sponsored by other organizations when the topic is of
keeninteresttothechemistryaudience.
Beforeagreeingtopublishabook,theproposedtableofcontentsisreviewed
forappropriateandcomprehensivecoverageandforinteresttotheaudience. Some
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comprehensiveness. When appropriate, overview or introductory chapters are
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andmanuscriptsarepreparedincamera-readyformat.
As a rule, only original research papers and original review papers are
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arenotaccepted.
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In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
Preface
Manganese(Mn)oxidesareamongthemostreactivemineralsintheearth’s
surface environment, and play a significant role in adsorption, co-precipitation
and redox reactions, affecting biogeochemical cycles of numerous nutrients and
contaminants. Inaddition,Mnoxidesarewidelyappliedasabsorbents,ionsieves,
chemical oxidants and catalysts for environmental remediation and pollution
control. Inthepast,significantadvancesinMnoxidegeochemistrywereachieved
on the occurrence and mineralogy of Mn oxides in various geological settings,
and greatly improved our ability to decipher the evolution processes, reactivity
andenvironmentalbehaviorofMnoxides. Thereare,however,stillmanyaspects
poorlyunderstoodintermsoftheenvironmentalgeochemistryofMnoxides,such
as biogenic formation mechanisms, detailed crystal structure of nanocrystalline
phases, electron transfer paths in redox reactions, adsorption mechanisms of
contaminants on surfaces, physiochemical factors controlling the contents of
structuralMn(III)andvacantsitesthatlargelydetermineMnoxidereactivity,and
theroleofMn(III)intheaboveprocesses. Itisincreasinglyrecognizedthatsuch
knowledgeiscriticalforbetterunderstandingbothbiogeochemicalprocessesand
environmentalapplicationsofMnoxides.
To better address the above knowledge gaps and present current advances
on geochemistry of Mn oxides in multiple scientific disciplines, we organized
a symposium entitled “Advances in Understanding the Environmental
Geochemistry of Manganese (Mn) Oxides” at the 247th American Chemistry
SocietyNationalMeetinginDallasonMarch16-20,2014. Thefullproceedings
of the symposium are available at http://geochemistrydivision.sites.acs.org/
acsspring2014sessions.htm. The symposium attracted approximately 100
scientists from the international environmental chemistry and geochemistry
communities. Thirty two speakers, including 20 distinguished invited speakers
gave presentations over two full-day oral sessions. Many cutting-edge findings
and novel methodologies were reported, representing the state-of-the-art in the
fieldofMnoxidegeochemistry.
This book is based on the invited papers presented at the symposium, and
aims to bring together advances on Mn oxide environmental biogeochemistry
from leading scientists in multiple disciplines, e.g., mineralogy, geochemistry,
soilscienceandenvironmentalengineering. Anumberoffrontierresearchtopics
are included in the book, such as in-situ characterization of Mn oxide reactivity
with As and Cr, kinetics and molecular-scale mechanisms of metal oxidation
by Mn oxides, mechanistic understanding of metal sorption through density
functiontheory,theroleofsurfaceedgesitesofbirnessitesinmetal(loid)sorption,
reactivity of natural crytomelane, pathways of phyllomanganate transformation
ix
In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
totodorokite,water-oxidationcatalysisbyMnoxides,insituAsimmobilization
usingstabilizedFe-Mnbinaryoxides,andsynthesisofLiion-sievesfrombiogenic
oxides and stability of colloidal Mn oxides. To the best of our knowledge, no
ACSsymposiumserieshasbeenpublishedonasimilartopicinthepast30years.
The book should be of interest to scientists and engineers in a broad range
of disciplines, such as geochemistry, soil science, mineralogy, microbiology,
materials science, and environment engineering, as well as graduate students
who are engaged in research on Mn oxide biogeochemistry and the engineering
applicationofMn-bearingmaterials. Itisalsotargetedforlibrariesintheabove
disciplines.
Theeditorswouldliketoacknowledgealltheauthorsofthechaptersfortheir
excellentcontributionandtheanonymousreviewersfortheirexcellentevaluation
ofthemanuscripts. WearealsogratefultotheACSBookseditors,TimMarney,
Bob Hauserman and Lindsey Watson, for their kind assistance and patience
throughoutthepublicationprocess. Wewouldliketothankallthespeakerswho
participatedinthesymposium.
XionghanFeng
Key Laboratory of Arable Land Conservation (Middle and Lower Reaches of
YangtseRiver),MinistryofAgriculture
CollegeofResourcesandEnvironment,HuazhongAgriculturalUniversity
Wuhan430070, China
[phone](telephone)
[phone](fax)
[email protected](e-mail)
Wei Li
KeyLaboratoryofSurficialGeochemistry,MinistryofEducation
SchoolofEarthSciencesandEngineering,NanjingUniversity
Nanjing210093, China
[phone](telephone)
[phone](fax)
[email protected](e-mail)
MengqiangZhu
DepartmentofEcosystemScienceandManagement
UniversityofWyoming
1000E.UniversityAve.,Laramie,WY82071
[phone](telephone)
[phone](fax)
[email protected](e-mail)
x
In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
DonaldL.Sparks
DelawareEnvironmentalInstitute(DENIN)
DepartmentofPlantandSoilScience,UniversityofDelaware
221AcademySt.,Suite250
Newark, DE19716
[phone](telephone)
[phone](fax)
[email protected](e-mail)
xi
In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
Editors’ Biographies
Xionghan Feng
Xionghan Feng, a Professor of Soil Chemistry, received a Ph.D. in soil
science and joined the faculty at the Huazhong Agricultural University in 2003.
He spent more than two years at the University of Delaware in the Delaware
EnvironmentalInstitute(DENIN)asavisitingscientistthrough2007to2012. His
research focuses on mineralogy, reactivity and environmental behaviors of Fe,
Mn and Al (hydr)oxides in soils. Projects include mineralization and evolution
ofactiveFe/Mnoxides,interfacialreactionsofcontaminantsandnutrientsatthe
surface of minerals and soil chemical processes regulating coupled cycling of
phosphorusandiron.
Wei Li
Wei Li is a Professor of geochemistry at the Nanjing University in the
DepartmentofEarthSciences. Hisresearchfocusesonmineral-waterinterfacial
geochemistry and soil metal biogeochemistry as well as the application
of fundamental principles of geochemistry in soil remediation and water
decontamination. Projects include exploring the mechanism of transition metals
precipitationonclayandAloxidessurfaceusingquick-scanningEXAFS,theuse
oflimestonemineralsandclaymineralsformetalsequestrationforcontaminated
soils in Southern China, and designing new materials for fluoride removal.
He is also interested in studying the soil phosphorus chemistry using both 31P
liquid-state and solid-state NMR spectroscopy. He has published 26 papers in
peer-reviewedjournalssuchasNatureCommunications, EnvironmentalScience
&Technology,andGeochemicalCosmochimicalActa.
Li holds a B.S. in chemistry from the Wuhan University, a M.S in
environmentalchemistryattheResearchCenterofEco-EnvironmentalSciences
of Chinese Academy of Sciences, and a Ph.D. in mineralogy and geochemistry
fromtheStateUniversityofNewYorkatStonyBrook. Heperformedapostdoc
attheUniversityofDelawareintheDelawareEnvironmentalInstitute(DENIN).
Mengqiang Zhu
Mengqiang Zhu is an assistant professor at the University of Wyoming in
the Department of Ecosystem Science and Management. His research include
1) structure, formation and reactivity of environmental minerals, including
manganese and iron oxides, 2) mineral-water interfacial processes, and 3)
phosphorusandsulfurcyclinginnaturalandagriculturalecosystems.
©2015AmericanChemicalSociety
In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.
MengqiangZhuholdsaB.S.inEnvironmentalEngineeringfromNorthChina
Electric Power University, M.S. in Environmental Chemistry from the Research
CenterforEco-EnvironmentalSciences,ChineseAcademyofSciences,andPh.D.
inEnvironmentalSoilChemistryattheUniversityofDelaware. Afterpostdoctoral
researchattheLawrenceBerkeleyNationalLaboratory,hejoinedthefacultyatthe
UniversityofWyomingin2013.
Donald L. Sparks
DonaldL.SparksistheS.HallockduPontChairinSoilandEnvironmental
Chemistry,FrancisAlisonProfessorandDirectoroftheDelawareEnvironmental
Institute at the University of Delaware. He is internationally recognized for
research on the kinetics of soil chemical processes, sorption mechanisms of
metal(loid)s and nutrients at the mineral/water interface, and speciation of
contaminants in soils. Sparks is the author of three textbooks, editor of several
books, and author of numerous book chapters and 235 refereed papers. He has
received numerous honors and awards including Fellow of five professional
societies, the Liebig Medal from IUSS, Einstein Professor from the Chinese
Academy of Sciences, the Soil Science Research Award, and the Geochemistry
MedalfromtheAmericanChemicalSociety.
200
In Advances in the Environmental Biogeochemistry of Manganese Oxides; Sparks, et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2015.