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About 1b UNIT-II AromaticAminesBasicityofamineseffectofsubstituentsonbasicityandsyntheticusesofaryldiazoniumsalts
The order of basicity of aliphatic amines is different in the gas phase and in aqueous solution. In the gas phase, the basicity increases with the number of alkyl groups attached to the nitrogen atom. This is because the alkyl groups donate electron density to nitrogen through inductive effect, making it more basic. However, in aqueous solution, the order is reversed - secondary amines are more basic than primary and tertiary amines. This is because in water, amines exist as ammonium ions. Primary and secondary ammonium ions undergo stronger solvation (hydrogen bonding) with water molecules compared to tertiary ammonium ions. This solvation effect increases the electron density on the nitrogen to a greater extent for primary and
Detailed Information
| Author: | ['Pooja Saini'] |
|---|---|
| Publication Year: | 2019 |
| Pages: | 17 |
| Language: | English |
| Format: | |
| Price: | FREE |
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