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1166..99 PPrreeppaarraattiioonn ooff EEppooxxiiddeess:: AA RReevviieeww aanndd aa PPrreevviieeww PPrreeppaarraattiioonn ooff EEppooxxiiddeess EEppooxxiiddeess aarree pprreeppaarreedd bbyy ttwwoo mmaajjoorr mmeetthhooddss.. BBootthh bbeeggiinn wwiitthh aallkkeenneess.. rreeaaccttiioonn ooff aallkkeenneess wwiitthh ppeerrooxxyy aacciiddss ((SSeeccttiioonn 66..1188)) ccoonnvveerrssiioonn ooff aallkkeenneess ttoo vviicciinnaall hhaalloohhyyddrriinnss,, ffoolllloowweedd bbyy ttrreeaattmmeenntt wwiitthh bbaassee ((SSeeccttiioonn 1166..1100)) 1166..1100 CCoonnvveerrssiioonn ooff VViicciinnaall HHaalloohhyyddrriinnss ttoo EEppooxxiiddeess EExxaammppllee HH HH OOHH NNaaOOHH OO HH OO HH 22 BBrr HH ((8811%%)) EExxaammppllee HH HH OOHH NNaaOOHH OO HH OO HH 22 BBrr HH ((8811%%)) •••• –– ••OO •• vviiaa:: •• •• HH HH ••BBrr •• •• •• •••• EEppooxxiiddaattiioonn vviiaa VViicciinnaall HHaalloohhyyddrriinnss BBrr BBrr 22 HH OO 22 OOHH aannttii aaddddiittiioonn EEppooxxiiddaattiioonn vviiaa VViicciinnaall HHaalloohhyyddrriinnss BBrr BBrr 22 NNaaOOHH HH OO 22 OO OOHH aannttii iinnvveerrssiioonn aaddddiittiioonn ccoorrrreessppoonnddss ttoo oovveerraallll ssyynn aaddddiittiioonn ooff ooxxyyggeenn ttoo tthhee ddoouubbllee bboonndd EEppooxxiiddaattiioonn vviiaa VViicciinnaall HHaalloohhyyddrriinnss BBrr HH CC 33 BBrr HH 22 NNaaOOHH HH CC HH 33 HH CCHH HH OO 33 HH 22 OO CCHH 33 OOHH aannttii iinnvveerrssiioonn aaddddiittiioonn ccoorrrreessppoonnddss ttoo oovveerraallll ssyynn aaddddiittiioonn ooff ooxxyyggeenn ttoo tthhee ddoouubbllee bboonndd EEppooxxiiddaattiioonn vviiaa VViicciinnaall HHaalloohhyyddrriinnss BBrr HH CC 33 BBrr HH CC HH HH 22 NNaaOOHH 33 HH CC HH 33 HH CCHH HH CCHH 33 HH OO 33 HH 22 OO CCHH 33 OOHH aannttii iinnvveerrssiioonn aaddddiittiioonn ccoorrrreessppoonnddss ttoo oovveerraallll ssyynn aaddddiittiioonn ooff ooxxyyggeenn ttoo tthhee ddoouubbllee bboonndd 1166..1111 RReeaaccttiioonnss ooff EEppooxxiiddeess:: AA RReevviieeww aanndd aa PPrreevviieeww

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Epoxides are prepared by two major methods. Both begin with alkenes. reaction of alkenes with peroxy acids (Section 6.18) conversion of alkenes to vicinal

16.9 Preparation of Epoxides: A Review and a Preview PDF

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Epoxides are prepared by two major methods. Both begin with alkenes. reaction of alkenes with peroxy acids (Section 6.18) conversion of alkenes to vicinal

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Author:	Unknown
Publication Year:	2001
Pages:	42
Language:	English
File Size:	0.06
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