Table Of ContentSilanes and Other Coupling Agents
Volume 4
TThhiiss ppaaggee iinntteennttiioonnaallllyy lleefftt bbllaannkk
Silanes and Other
Coupling Agents
Volume 4
Edited by
K.L. Mittal
LEIDEN (cid:121) BOSTON
2007
CRC Press
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Contents
Preface ix
Part 1. Silane Coupling Agents
Are silane films water barriers?
G. Pan and D. W. Schaefer 3
Differentiation of silane adsorption onto model E-glass surfaces from
mixed solutions of amino and glycidyl silanes
X. M. Liu, J. L. Thomason and F. R. Jones 17
The differential adsorption of silanes from solution onto model
E-glass surfaces using high-resolution XPS
F. R. Jones, X. M. Liu and J. L. Thomason 29
Characterization of the interaction between silanes and solid surfaces
by the streaming potential method
C. Bellmann, R. Plonka, A. Caspari and T. Luxbacher 39
Thermal characterization of the interaction of silanes with a
dihydroxy vulcanized fluoroelastomer
M. B. Sands, V. Subramanian and G. Mao 49
Modeling and practice of ethanol devolatilization from silica–silane
rubber compounds in an internal mixer
W. Dierkes and J. W. M. Noordermeer 67
The effect of trialkoxysilane coupling agent coatings on E-glass
fibers on the flexural properties of fiber-reinforced composites
J. P. Matinlinna, J. E. Dahl, L. V. J. Lassila and P. K. Vallittu 83
Glass strengthening by organosilane water-based coatings
R. Briard, E. Barthel, G. Laurent and C. Heitz 99
Glass substrates modified with organosilanes for DNA
immobilization
A. Carré, W. Birch and V. Lacarrière 113
vi Contents
Surface photografting of unsaturated alkoxysilanes onto polyolefins
with excimer-UV lamps
T. Textor, K. Opwis, T. Bahners and E. Schollmeyer 127
Surface functionalization of textile fibers with reactive silanes
T. Bahners, T. Textor and E. Schollmeyer 141
Localization of octadecyltrimethoxysilane self-assembled
monolayers by a combination of bottom-up and top-down
approaches
B. Viallet, C. Martin, L. Ressier, J. Grisolia and J. P. Peyrade 153
Self-assembled monolayers of omega-functional silanes:
A platform for understanding cellular adhesion at the molecular level
M. H. Lee, D. Boettiger, P. Ducheyne and R. J. Composto 163
Stability enhancement of polystyrene thin films on
aminopropyltriethoxysilane ultrathin layer modified surfaces
S.-H. Choi, Y. Cai and B.-m. Zhang Newby 179
Applications of trialkoxysilanes in dental biomaterials: A review
J. P. Matinlinna, M. Özcan, L. V. J. Lassila and P. K. Vallittu 199
Part 2. Silanes for Corrosion Inhibition/Protection
Electrodeposition of aromatic bis-silanes for pretreatment of
aluminum alloys
S. Chandrasekaran, W. J. van Ooij and T. L. Metroke 219
Performance of silanes in protecting metals from corrosion:
Effect of substrate cleaning
R. Nookala, Y. Wang and W. J. van Ooij 231
Improved water-based silane pretreatment for hot-dip galvanized
steel substrates
C. Shivane, N. B. V. Simhadri and W. J. van Ooij 253
Integral epoxy resin–silane primer system for hot-dip galvanized
steel
W. J. van Ooij, K. Suryanarayanan and T. L. Metroke 275
Corrosion inhibitors for silane systems on aluminum alloys
L. Yang, N. Simhadri, A. Seth and W. J. van Ooij 287
A novel low-VOC, chromate free, one-step primer system for
corrosion protection of metals and alloys
A. Seth and W. J. van Ooij 307
Contents vii
An ultra-flexible, chromate-free, low-VOC, silane-based finishing
and coating system for corrosion protection of aluminum alloys
A. Ashirgade, T. Mugada and W. J. van Ooij 331
Part 3. General Papers
Well-defined polymer–Si/SiO hybrids via surface-initiated atom
2
transfer radical polymerization and their relevance to
nanotechnology
G. D. Fu, F. J. Xu, E. T. Kang and K. G. Neoh 355
Incorporation of the macrocyclic ligand cucurbit[6]uril into a silica
matrix
H.-J. Buschmann, A. Wego, E. Schollmeyer, M. Felicetti,
A. M. Richter and S. Jähnert 373
Effect of the post-application of polysiloxanes on plasma-treated
wool fabrics
C. Canal, R. Molina, E. Bertrán and P. Erra 383
Comparative studies of hydrophobic surface treatments for TiO :
2
n-octylphosphonic acid and n-octyltriethoxysilane
A. A. Parker, J. Hollenberg, J. J. Marcinko, P. Rinaldi and
T. Wagler 399
TThhiiss ppaaggee iinntteennttiioonnaallllyy lleefftt bbllaannkk
Silanes and Other Coupling Agents, Vol. 4, pp. ix–x
Ed. K.L. Mittal
© VSP 2007
Preface
This book documents the proceedings of the Fifth International Symposium on Si-
lanes and Other Coupling Agents held under the aegis of MST Conferences, LLC
in Toronto, Canada, June 22–24, 2005. The premier symposium on this topic was
held in honor of the 75th birthday of Dr. Edwin P. Plueddemann in Midland, MI,
April 3–5, 1991 the proceedings of which were properly chronicled in a hard-
bound book [1]. The second symposium in this series (with a slightly different ti-
tle) was held under the auspices of C4 Technologies, Inc. in Newark, NJ, October
21–23, 1998 and the proceedings were also embodied in a book form [2]. Apro-
pos, it should be recorded that the third symposium in this vein was organized by
MST Conferences, LLC in Newark, NJ, June 18–20, 2001 but, for a variety of
reasons, the proceedings of this event were not documented in the form of a hard-
bound book. The fourth symposium on this topic was also organized by MST
Conferences, LLC in Orlando, FL, June 11–13, 2003 the proceedings of which
were documented in a hard-bound book [3].
The topic of silanes and other coupling agents is of tremendous contemporary
interest and even a casual look at the literature will attest that there is a brisk
R&D activity in this arena. This high tempo of activity and interest emanates
from the application of these materials to promote adhesion in a variety of highly
technologically important areas, e.g., coatings, adhesive bonding, reinforced
polymer composites, nanocomposites, textiles, dental materials and biomedical.
So the importance of understanding the mechanisms by which these materials
function and developing new and improved adhesion promoters is quite patent.
Besides their role in improving adhesion, currently there is much interest in har-
nessing these materials for corrosion inhibition/protection of various metals and
alloys.
The technical program for this event comprised 43 papers reflecting both over-
views and original research contributions. The presenters hailed from academia,
industry and other research organizations from many corners of the globe. The
presentations covered many ramifications of these materials and both fundamental
and applied aspects were accorded due coverage.
Now turning to this volume, it contains a total of 26 papers, other are not in-
cluded for a variety of reasons, which were rigorously peer reviewed, revised
(some twice or thrice) and edited. So it should be recorded that this book is not a
mere collection of papers – which is normally the case with many proceedings
volumes – rather it represents the highest standard of publication. The book is di-
vided into three parts: Part 1. Silane Coupling Agents; Part 2. Silanes for Corro-
