Nanostructured Materials and Coatings for Biomedical and Sensor Applications

393 Pages·2003·21.87 MB·English

by  I. Uvarova (auth.)

Nanostructured Materials and Coatings for
Biomedical and Sensor Applications
NATO Science Series
A Series presenting the results of scientific meetings supported under the NATO Science
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Series II: Mathematics, Physics and Chemistry - Vol. 102
Nanostructured Materials and
Coatings for 8iomedical and
Sensor Applications
edited by
Y.G. Gogotsi
Drexel University,
Department of Materials Engineering,
Philadelphia, U.SA
and
Iri na V. Uvarova
Institute for Problems of Materials Science,
National Academy of Science,
Kiev, Ukraine
....
"
Springer Science+Business Media, B.v.
Proceedings of the NATO Advanced Research Workshop on
Nanostructured Materials and Coatings for Biomedical and Sensor Applications
Kyiv, Ukraine
4-8 August 2002
A C.I.P. Catalogue record for this book is available from the Library of Congress.
ISBN 978-1-4020-1321-8 ISBN 978-94-010-0157-1 (eBook)
DOI 10.1007/978-94-010-0157-1
Printed on acid-free paper
AII Rights Reserved
© 2003 Springer Science+Business Media Dordrecht
Originally published by Kluwer Academic Publishers in 2003
Softcover reprint of the hardcover 1s t edition 2003
No part of this work may be repraduced, stored in a retrieval system, or transmitted
in any form or by any means, electronic, mechanical, photocopying, microfilming,
recording or otherwise, without written permission fram the Publisher, with the exception
of any material supplied specifically for the purpose of being entered
and executed on a computer system, for exclusive use by the purchaser of the work.
Contents
Preface ......................................................................................................................... ix
Group photo ................................................................................................................. xi
Chapter 1. Materials for Biomedical Applications
"Nanostructured Materials in Medicine. State of the Art in Ukraine"
I. Uvarova ................................................................................................................ 1
"Current Trends in Biomaterial Coatings"
S.V. Mikhalovsky, M. Santin, L.I. Mikhalovska, A.W. Lloyd, S.P. Denyer ........ 15
"Injectable Nanoparticle Technology for In Vivo Remediation of Overdosed
Toxins"
R. Partch, E. Powell, Y.-H. Lee, M. Varshney, S. Kim, N. Barnard, D. Shah,
D. Dennis, T. Morey ............................................................................................. 27
"Nanostructured MeSi02 (Me=Ag, Cu) Coatings with Antibacterial Activity"
C.C. Trapalis, T. Vaimakis, A. Kharlamov, M. Kokkoris, G. Kordas ................... 41
"Low Friction Wear Resistant Sputtered Carbon Coatings for Biomedical
Applications"
S.K. Taylor, A.H.S. Jones, D. Meres, D.G. Teer, M. Elloy .................................... 51
"Mechanism of Interaction of Silicon Nitride Powders with Biochemical
Media and Their Toxic Effect"
V.A. Lavrenko, N.V. Boshitskaya, G.N. Makarenko ............................................ 63
"Microstructure and Strength Properties of Germanium Microwires for
Biomedical Devices"
D. Grabco, M. Dyntu, D. Meglei, O. Shikimaka ................................................... 71
vi
"The Researches of Properties of Biomaterials Based on Biological
Hydroxyapatite in Synthetic and Natural Physiological Mediums"
L.A. Ivanchenko, N.D. Pinchuk, V.S. Sulyma ..................................................... 77
"Preparation of Hydroxyapatite NanoParticles Using a Modified Precipitation
Method"
G. C. Koumoulidis, C. C. Trapalis, A. T. Sdoukos, and T. C. Vaimakis .............. 83
"Biomineralization of Hydroxyapatite/Titania Composites Prepared by
Explosive Shock Waves"
H. Beheri, Wafa 1. Abdel-Fattah, R. Pruemmer. .................................................... 91
"Prospects of Usage of Materials with Fullerene Coatings for Endoprosthesis
of Joints"
V.V. Lashneva, Yu.G. Tkachenko, V.A. Dubok, D.V. Schur, V.V. Sychev,
L.A. Matveeva ..................................................................................................... 103
"Nanodispersed Diamond Adsorbents for Biological Solution Cleaning"
G.P. Bogatyreva, M.A. Marinich, N.A. Oleynik, G.A. Bazaliy .......................... lll
Chapter 2. Thin Films and Coatings
"Tribological Characterization of Carbide-Derived Carbon (CDC) Films in
Dry and Humid Environments"
B. Carroll, Y. Gogotsi, A. Kovalchenko, A. Erdemir, M.J. McNallan ................ 119
"Nanostructured Ceramic Coatings Produced By Magnetron Sputtering"
V. Teixeira ........................................................................................................... 131
"Analysis of the Microhardness and the Porosity in Graded Thermal Barrier
Coatings"
A. Portinha, V. Teixeira, J. Martins, M.F. Costa, R. Vassen, D. Stoever. ........... 149
"Nanostructured Mesoporous Silica Films"
M.C. Gonyalves, G.S. Attard ............................................................................... 159
"Thin Film Crystallisation Behaviours for Oxides of Rare-Earth Metals on
Amorphous Silica"
A.F. Andreeva, A.M. Kasumov ........................................................................... 169
"Structure and Mechanical Properties of Nanostructured Metal-Carbon Films"
Y. Pauleau, F. Thiery, J. Pelletier, V.V. Uglov, A.K. Kuleshov, S.N. Dub,
M.P. Samtsov ....................................................................................................... 175
Vll
"Thin Film Metal Matrixes for Biocorrosion Studies"
O.K. Dvoynenko, LA. Kozlova, V.M. Statsenko ................................................ 181
Chapter 3. Nanoparticles and Nanoceramics
"Synthesis and Properties ofNanostructured Carbon Materials: Nanodiamond,
Onion-Like Carbon and Carbon Nanotubes"
V.L. Kuznetsov, Yu.V. Butenko ........................................................................... 187
"Synthesis of Spherical, Non-aggregated Silica Nanoparticles"
A. Vital, U. Klotz, F. Graule, R. Mueller, H.K. Kammler, S.E. Pratsinis ........... 203
"Formation of Composite SiC-SiB6 Nanopowders"
M. Lasova, M. Kakazey, 1.G. Gonzales-Rodriguez, G. Dominguez,
T. Tomila, L. Isaeva, L. Domasevich, A. Myratova ............................................ 211
"A Model of Electrical Conduction in Xerographic Toners as Polymer
Conductive Filler Particulate Composites"
V. Skorokhod ....................................................................................................... 219
"Computerized Complex for Sintering Nanoceramics at High Pressures"
V.S. Urbanovich, G.G. Shkatulo .......................................................................... 229
"C60 Fullerene Polymers"
R.A. Wood, M.H. Lewis, M.R. Lees, S.M. Bennington, M.G. Cain,
N. Kitamura .......................................................................................................... 239
"A Tight-Binding Molecular-Dynamics Approach to Structural and Electronic
Properties of a-SiC"
V.1. lvashchenko, P.E.A. Turchi, V.I. Shevchenko ............................................. 249
"Theory of Nanotube Nanodevices"
S.V. Rotkin .......................................................................................................... 257
Chapter 4. Sensor Materials
"Sol-Gel Processing of Lithia Aluminosilicates (LAS) Solid Solution for
Future Low Temperature Ceramic Sensor"
Wafa I. Abdel-Fattah, M.Sh. Fayed, Sh.R. Gouda, W.F.F. Mekky ..................... 279
"Structural and Optical Characterization of InN Thin Films - Novel Photonic
Materials for Photovoltaic and Sensor Applications"
V. Ya. Malakhov .................................................................................................. 29I
Ylll
"An Overview to Magnetic Beads Used in Electrochemical DNA Biosensors"
J. Wang, A. Erdem ............................................................................................... 297
"Mechanical Properties of Oxide Coatings Having Sensor Application"
D. Grabco, N. Palistrant, R. Jitaru, E. Rusu ......................................................... 305
"Approaches for Structured Immobilisation of Recognising Elements on the
Transducer Surface of Biosensors"
V.M. Starodub, A.V. Nabok, N.F. Starodub, L.I. Pirogova, W. Torbicz,
A.K. Ray .............................................................................................................. 311
"Performance of Amperometric Alcohol Electrodes Prepared by Plasma
Polymerization Technique"
D. <;6keliler and M. Mutlu ................................................................................... 327
"Chemical Active Centers at Surfaces ofSi-Based Materials"
A.E. Kiv, V.G. Litovchenko, D. Fuks, V.V. Golovanov, I.P. Lisovskyy,
T.I. Maximova ..................................................................................................... 333
"Deposition of Sn02-Based Thin Films by Reactive DC Magnetron
Sputtering for Gas Sensing Applications"
1. Miguel Correia-Pires, V. Teixeira, J.B. Almeida ............................................. 343
"Rehybridization at (110) Faces of Sn02 based gas sensor"
V.V. Golovanov, T.T. Rantala. T.S. Rantala, A. Kiv .......................................... 357
"Behaviour of Micro-Fabricated Composite Membrane as Amperometric
Glucose Biosensor"
eM. Pereira, J.M. Oliveira, F.Silva ................................................................... 365
"EQCM Study on the Polytyramine Modified Electrodes for the Preparation
of Biosensors"
eM. Cordas, A. Tenreiro, L.M. Abrantes ........................................................... 371
"Nanocoating of Particulate Surface in Colloidal Processing for Piezoelectric
Sensors Applications"
Wie-Heng Shih, Wna Y. Shih, Chia-Yi Yang, Huiming Gu, Jeong W. Yi ......... 377
Subject Index ............................................................................................................ 395
Preface
This volume contains papers that were presented at the NATO Advanced Research
Workshop on Nanostructured Materials and Coatings for Biomedical and Sensor
Applications held in Kyiv, Ukraine, 4-8 August, 2002. A total of 104 scientists from 14
countries participated in our ARW, making it a really international event. Participants
ranged from graduate students to senior researchers. They presented 16 tutorial lectures,
20 short talks and more than 70 posters. Invited speakers, from NATO and Partner
countries, presented some of the most recent developments in physics, chemistry and
technology of nanosized materials. A broad range of speakers having international
standing and representing NATO and partner countries, as well as university, industrial
and govemment research laboratories participated in this meeting and wrote papers for
this volume.
Foregoing ARW gathered together the scientists working in the area of nanosized
materials and coatings and their applications in biomedicine and sensors. The first
objective of this AR W was to discuss the current research covering a wide range of
physical and chemical properties of biomaterials and their use. Active discussion of oral
presentations and posters, and the round table discussion gave a good opportunity to
researchers from academia and industry to discuss the achievements in this field and
outline future directions in terms of technological developments and product
commercialisation in the fields of biomedicine and sensors. Particularly, advanced
ceramics and nanostructured carbons were covered in many presentations.
This ARW emphasized the connections between the physical, chemical and processing
data for nanosized materials, coatings and films. This AR W brought together scientists
from basic and applied research areas to initiate interactions aimed at translating basic
research achievements into engineering applications.
The workshop demonstrated that achievements in biomedical tt:chnology require
multidisciplinary research efforts. Those range from chemistry of complex oxide systems,
to physics and chemistry of different methods for their preparation and characterization,
mechanics of such systems and finally investigation of their interaction with, release of or
binding with biologically active (pharmaceuticals or toxins) molecules. Controlled
release concepts for delivery of pharmaceuticals are mature and employed commercially.
Along with the different methods for selective and controlled delivery of medicine to
traumatized parts of human tissue, the removal of overdosed drugs in vivo is a very
important problem which only recently received attention. One of the most revolutionary
trends of material evolution for the past four decades is the innovative use of special
ceramics designed to reproduce different functions of living organisms, to deliver and
regulate medications and to investigate the processes of formatting and functioning of
bioplast. New interesting information in these areas was reported by the participants
from Egypt, USA, Israel, Ukraine, Portugal, Turkey and other countries. Particular
attention was dedicated to carbon nanotubes, fullerenes, nano-to-microscale carbon films,
which can be extremely useful in meeting the increasingly multifunctional needs of
advanced mechanical devices and have excellent biocompatibility.
ix
x
This volume is complementary to various specialized books (for example, on
nanopowders, sensors, or biomaterials) or more general books on nanomaterials or
nanotechnology. It aims to present an overview of research activities in nanostructured
materials for biomedical and sensor applications. All papers included in this book have
been peer-reviewed prior to publication. Some of the contributed papers will be
published in the special issues of Journal of Materials Processing and Manufacturing
Science and Poroshkovaya Metallurgiya.
This volume will be of interest for researchers and graduate students working in the area
of materials science and engineering, nanotechnology, biomaterials and sensors. It can
also be useful for engineers interested in production and use of relevant materials.
We acknowledge the contribution of the Director of Institute for Problems of Materials
Science Prof. V.V. Skorokhod and the members of the local Organizing committee Dr. L.
Kolomiets and Dr. T. Babutina for making this ARW a successful and smoothly running
meeting, and Mr. C. Avila for his help with editing this volume. Finally, we express our
sincere gratitude to the NATO Science Committee for granting us an award to organize
this meeting. Some of the administrative costs were borne by the Science and Technology
Center Ukraine, Drexel University and the Institute for Problems of Materials Science of
the National Academy of Science, Ukraine.
Yury Gogotsi Irina V. Uvarova
~ 1Jf/I
Department of Materials Engineering Institute for Problems of Materials Science
Drexel University National Academy of Science
Philadelphia, PA 19104, USA Kyiv 03142, Ukraine