Macromolecular Nanostructured Materials

351 Pages·2004·5.2 MB·English

by  Hsian-Rong Tseng

SpringerSeries in
MATERIALS SCIENCE
SpringerSeries in
MATERIALS SCIENCE
Editors: R.Hull R.M.Osgood,Jr. J.Parisi H.Warlimont
The Springer Series in Materials Science covers the complete spectrum of materials physics,
includingfundamentalprinciples,physicalproperties,materialstheoryanddesign.Recognizing
theincreasingimportanceofmaterialsscienceinfuturedevicetechnologies,thebooktitlesinthis
series reflectthestate-of-the-artinunderstandingandcontrollingthestructureand properties
ofallimportantclassesofmaterials.
61 FatigueinFerroelectricCeramics 70 Applicationsofthe IsotopicEffect
andRelatedIssues inSolids
ByD.C.Lupascu ByV.G.Plekhanov
62 Epitaxy 71 DissipativePhenomena
PhysicalPrinciples inCondensedMatter
andTechnicalImplementation SomeApplications
ByM.A.Herman,W.Richter,andH.Sitter ByS.Dattaguptaand S.Puri
63 Fundamentals 72 PredictiveSimulation
ofIon-IrradiatedPolymers ofSemiconductorProcessing
ByD.Fink StatusandChallenges
Editors:LDabrowskiand E.R.Weber
64 MorphologyControlofMaterials
andNanoparticles 73 SiCPowerMaterials
AdvancedMaterials Processing DevicesandApplications
and Characterization Editor: Z.C.Feng
Editors:Y.Wasedaand A.Muramatsu
74 PlasticDeformation
65 TransportProcesses inNanocrystallineMaterials
inIon-IrradiatedPolymers ByM.Yu.Gutkin and LA.Ovid'ko
ByD.Fink
75 WaferBonding
66 MultiphasedCeramicMaterials Applications and Technology
ProcessingandPotential Editors:M.Alexeand U.G6sele
Editors:W.-H.Tuanand ].-K.Guo
76 SpirallyAnisotropicComposites
67 Nondestructive ByG.E.Freger,V.N.Kestelman,
MaterialsCharacterization and D.G.Freger
WithApplicationstoAerospaceMaterials
Editors: N.G.H.Meyendorf, P.B.Nagy, 77 ImpuritiesConfined
inQuantumStructures
and S.1.Rokhlin
ByP.O.Holtzand Q.X.Zhao
68 DiffractionAnalysis
78 MacromolecularNanostructured
oftheMicrostructureofMaterials
Materials
Editors:E.].Mittemeijerand P.Scardi
Editors:N.Ueyamaand A.Harada
69 Chemical-MechanicalPlanarization
ofSemiconductorMaterials
Editor: M.R.Oliver
N. Ueyama A. Harada (Eds.)
Macromolecular
Nanostructured
Materials
With 187Figures, 59Schemes and 26 Tables
8
~
Kodansha Springer
ProfessorNorikazuUeyama
ProfessorAkiraHarada
OsakaUniversity
GraduateSchoolofScience
DepartmentofMacromolecularScience
Toyonaka,Osaka560-0043
Japan
E-mails:[email protected]
[email protected]
SeriesEditors:
ProfessorRobertHull ProfessorIürgenParisi
UniversityofVirginia UniversitätOldenburg,FachbereichPhysik
Dept.ofMaterialsScienceandEngineering Abt. Energie-undHalbleiterforschung
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MicroelectronicsScienceLaboratory InstitutfürFestkörper-
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©NorikazuUeyarna,AkiraHaradaandSpringer-VerlagBerlinHeidelberg2004
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List of Contributors
Numbersinparenthesesrefertothesections.
Aoshima,Sadahito(2.5)
Department of Macromolecular Science, Graduate School of Science, Osaka
University, Machikaneyama,Toyonaka560-0043,Japan
Celestre,Paul C. (1.1)
Department of Chemistry and Biochemistry University of California, Los
Angeles,405 HilgardAvenue, LosAngelesCA 90095,USA
Chujo, Yoshiki (3.4)
Department of Polymer Chemistry, Graduate School of Engineering, Kyoto
University,Katsura,Nishikyo-ku, Kyoto 615-8510, Japan
Fuhrhop,Jurgen-Hinrich (3.1)
Institut flirOrganischeChemie der Freien UniversitatBerlin,Takustrasse 3,D
14195 Berlin,Germany
Gronwald, Oliver(2.3)
Asahi Kasei Corporation, SIF Research Group, Central Technology
Laboratory, Samejima,Fuji,Shizuoka416-8501,Japan
Hanabusa, Kenji (2.4)
Graduate School of Science and Technology, Shinshu University, Tokida,
Ueda 386-8567,Japan
Harada, Akira(1.2,4.2)
Department of Macromolecular Science, Graduate School of Science, Osaka
University,Machikaneyama,Toyonaka560-0043,Japan
Hirao, Toshikazu(3.2)
Department of Applied Chemistry, Graduate School of Engineering, Osaka
University,Yarnada-oka, Suita 565-0871,Japan
Khodabakhsh, Saghar(1.3)
Department of Chemistry, Imperial College of Science, Technology and
Medicine,South Kensington, London SW7 2AY, UK
vi ListofContributors
Kim, Kyung-Min (3.4)
Department of Polymer Science & Engineering, Chungju National University,
123Geomdan-ri, Iryu-myeon, Chungju, Chungbuk,380-702,Korea
Klyszcz, Andreas (3.1)
Institut furOrganische Chemie derFreien Universitat Berlin,Takustrasse 3,D
14195Berlin,Germany
Koumoto,Kazuya (4.4)
Department of Chemical Processes and Environment, Faculty of
Environmental Engineering, University of Kitakyushu, Wakamatsu-ku,
Kitakyushu808-0135, Japan
Krasia,Theodora(1.3)
Max Planck Institute for Colloids and Interfaces, Golm 14424 Potsdam,
Germany
Liaw,Der-Jang (2.2)
Department of Chemical Engineering, National Taiwan University of Science
andTechnology, Taipei,Taiwan
Lauer, Matthias(3.1)
InstitutfurOrganische Chemie derFreien Universitat Berlin,Takustrasse3,D
14195Berlin,Germany
Li,Guangtao(3.1)
InstitutfurOrganische Chemie derFreien Universitat Berlin,Takustrasse3,D
14195Berlin,Germany
Michinobu, Tsuyoshi(2.1)
Department of Applied Chemistry, Waseda University, Shinjuku-ku, Tokyo
169-8555,Japan
Murata,Masaki(3.5)
Department of Chemistry, Graduate School of Science, The University of
Tokyo, Bunkyo-ku,Tokyo 113-0033,Japan
Nishide, Hiroyuki (2.1)
Department of Applied Chemistry, Waseda University, Shinjuku-ku, Tokyo
169-8555,Japan
ListofContributors vii
Nishihara,Hiroshi (3.5)
Department of Chemistry, Graduate School of Science, The University of
Tokyo,Bunkyo-ku,Tokyo 113-0033,Japan
Okamura,Taka-aki (3.6)
Department of Macromolecular Science, Graduate School of Science, Osaka
University,Machikaneyama,Toyonaka560-0043,Japan
Osaki,Shigeyoshi(4.5)
Department of Chemistry, Faculty of Medicine, Nara Medical University,
Shijo-cho, Kashihara634-8521,Japan
Reedijk,Jan (4.1)
Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University,
P.O.Box9502,2300 RALeiden,The Netherlands
Sakurai, Kazuo (4.4)
Department of Chemical Processes and Environment, Faculty of
Environmental Engineering, University of Kitakyushu, Hibikino, Wakamatsu
ku,Kitakyushu808-0135,Japan
Shinkai,Seiji (2.3,4.4)
Department of Chemistry and Biochemistry, Graduate School of Engineering,
KyushuUniversity,Higashi-ku,Fukuoka 812-8581,Japan
Steinke,Joachim H.G.(1.3)
Department of Chemistry, Imperial College of Science, Technology and
Medicine,South Kensington,LondonSW7 2AZ,UK
Stoddart,J. Fraser (1.1)
Department of Chemistry and Biochemistry, University of California, Los
Angeles405 Hilgard Avenue,LosAngelesCA90095,USA
Toshima,Naoki(3.3)
Department of Materials Science and Environmental Engineering, Faculty of
Science and Engineering, Tokyo University of Science, Yamaguchi [The for
mer Science University of Tokyo in Yamaguchi], Daigaku-dori, Onoda 756
0884,Japan
viii ListofContributors
Tseng,Hsian-Rong (1.1)
Department of Chemistry and Biochemistry, University of California, Los
Angeles,405 Hilgard Avenue,LosAngelesCA90095, USA
Tuncel,Doniis(1.3)
DepartmentofChemistry, Bilkent University,06800 Bilkent,Ankara,Turkey
Ueyama,Norikazu (3.6,4.3)
Department of Macromolecular Science, Graduate School of Science, Osaka
University,Machikaneyama,Toyonaka 560-0043,Japan
Yamaguchi, Hiroyasu(4.2)
Department of Macromolecular Science, Graduate School of Science, Osaka
University, Machikaneyama,Toyonaka 560-0043,Japan
Yamamoto,Hitoshi (4.3)
Department of Macromolecular Science, Graduate School of Science, Osaka
University,Machikaneyama,Toyonaka560-0043, Japan
Preface
This volume contains information on the most recent advances in the rapid
development of nanostructured materials. The authors are world leaders in this
areaand agroup of young scientists who havedevoted themselves tothedevelop
mentof macromolecular nanostructured materials.The first development phase of
this field was characterized by the construction of nanostructured materials. We
have now entered the second phase, the aim of which has been the creation of a
functional devicefor variousapplications.Polymeric materials have alreadyestab
lishedananosized structure forthese infinitesimal purposes. However, thesepoly
mersare usedviaatop-down processing approach from the mass.Thegoal ofcre
ating new nanostructured materials is to produce instead a device which can be
self-assembled and used in a bottom-up processing approach. Although the top
down processing approach has given rise to the problem of how to dispose of
scrapsgenerated byindustrial anddaily usage,thebottom-up processing approach
willinvolve aspecific reaction after usage,therebyeliminating this disposal prob
lem.
The collected articles present important concepts for the precise synthesis of
nanostructured materials. These small molecules are designed according to the
molecular recognition results for their functions, such as molecular electronics,
mesoscopic assemblies using organic building blocks or polymers with well
defined shape, size and adeeply buried functional group, and novel magnets con
sisting oforganic radicals, sol-gelhybrids applicable for hardeners offluids orliq
uid crystals. The second part mainly describes macromolecular metal complexes
and their assemblies having high ability in redox and catalytic reactions and
mechanical hardness as well as and the nanostructured assemblies of inorganic
polymers thatcontain various metalcomplex units.The third part deals with bio
logically-relevant nanostructured assemblies of DNA-metal, DNA-organic poly
mer,fibrillate proteins andbiominerallization.
Theaim ofthis volume istounderstand thesynthetic foundations forthecon
struction of macromolecular nanostructured materials and to describe the reviews
and results of each research project supported as frontier topics. This volume
endeavors to serve as areference work notonlyfor specialists and non-specialists
but also for graduate students who are interested in learning about national pro
jects conducted incountries all around the world.By including articles from vari
ous different scientific backgrounds, we hope that this will increase the knowl
edgeofthereaders andimpressuponthemthescopeofthefieldofnanoscience.
This monograph started out simply as a paper presented at the Osaka
UniversityMacromolecularSymposium inOsaka (November 5-7,2001).Because
of thegreat strides made recently in nanoscience, it wasconsidered appropriate to
expand thispaper intoacomplete book.Someoftheconcepts basedonnanostruc
tured material science have stimulated themain subjects of the 21stCentury COE