Table Of Contentइंटरनेट मानक
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timely dissemination of this information in an accurate manner to the public.
“जान1 का अ+धकार, जी1 का अ+धकार” “प0रा1 को छोड न’ 5 तरफ”
Mazdoor Kisan Shakti Sangathan Jawaharlal Nehru
“The Right to Information, The Right to Live” “Step Out From the Old to the New”
IS 14249 (1995): Etofenprox, Technical [FAD 1: Pesticides
and Pesticides Residue Analysis]
“!ान $ एक न’ भारत का +नम-ण”
Satyanarayan Gangaram Pitroda
““IInnvveenntt aa NNeeww IInnddiiaa UUssiinngg KKnnoowwlleeddggee””
“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता हहहहै””ै”
Bhartṛhari—Nītiśatakam
“Knowledge is such a treasure which cannot be stolen”
IS 14249 : 1995
v7dklm
T’\ ‘\
JrJ[l+) r L&-#-J- t (-Jq),+-& -m
Indian Standard
ETOFENPROX, TECHNICAL -
SPECIFICATION
UDC 632.951 El-H
0
BIS 1995
BUREAU OF INDIAN STANDARDS
MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG
NEW DELHI 110002
March 19%
PriceGroup 2
sedicitseP lanoitceS ,eettimmoC DAF 1
FOREWORD
sihT naidnI dradnatS saw detpoda yb eht uaeruB fo naidnI ,sdradnatS retfa eht tfard dezilanif yb eht
sedicitseP lanoitceS ,eettimmoC dah neeb devorppa yb eht dooF dna erutlucirgA noisiviD .licnuoC
,xorpnefotE lacinhcet si deyolpme ni eht noitaraperp fo ladicitcesni .snoitalumrof
xorpnefotE si eht nommoc eman desoporp yb eht lanoitanretnI noitazinagrO rof noitazidradnatS )OSI(
rof lyznebyxonehp-3 )lynehpyxohte-lr(-Z lyhtem-2 lyporp ,rehte eht laciripme dna larutcurts ealumrof dna
ralucelom ssam fo xorpnefote are nevig :woleb
Empirical Formula StructuralF ormula Molecular Mass
-0
0 \/
-3\5
-o
5H2C Cl CH2
30312Hs2C 74.673
nI eht noitaraperp fo siht ,dradnats eud noitaredisnoc sah neeb nevig ot eht snoisivorp fo eht
Insecticides
1968 dna eht demarf rednuereht dna
Act, Rules Standards of Weights and Measures (Packaged Com-
,revewoH siht dradnats si tcejbus ot eht snoitcirtser desopmi rednu eseht reverehw
modties) Rules, 1977.
.elbacilppa
roF eht esoprup fo gnidiced rehtehw a ralucitrap tnemeriuqer fo siht dradnats si deilpmoc ,htiw eht lanif
,eulav devresbo ro ,detaluclac gnisserpxe eht tluser fo a tset ro ,sisylana llahs eb dednuor ffo ni ecnadrocca
htiw SI 2 : lXX!l seluR‘ rof gnidnuor ffo laciremun seulav (revised)‘. The rebmun fo tnacifingis secalp
deniater ni eht dednuor ffo eulav dluohs eb eht emas as taht fo eht deificeps eulav ni siht .dradnats
Is 14249 : 1995
Indian Standard
ETOFENPROX, TECHNICAL -
SPECIFICATION
EPOCS 4 GNIKCAP
1
sihT dradnats sebircserp eht stnemeriuqer dna eht ehT lairetam llahs eb dekcap ni edarg ’A‘ .S.M
sdohtem fo gnilpmas dna tset rof ,xorpnefote -hcet sreniatnoC ylbatius dereuqcal moFf edisni dna
.lacin dedivorp htiw reflip foorp resolc .metsys ehT -ixam
mum yticipac fo eht .S.M sreniatnoC llahs eb
2 SECNEREFER
200 .gk tI llahs osla mrofnoc ot eht lareneg re-
ehT naidnI sdradnatS detsil woleb are yrassecen tnemeriuq nevig ni SI 8190 (Part 1) : 1988.
stcnujda ot siht :dradnats
5 GNIKRAM
SI .oN eltiT
5.1 ehT sreniatnoc llahs eb dekram ylbigel dna
6940 : 1982 sdohteM fo tset rof sedicitsep dna ylbiledni htiw eht gniwollof :noitamrofni
rieht snoitalumrof (jirst revision) a) emaN fo eht ;lairetam
8190 (Part 1) : tnemeriuqeR rof gnikcap fo b) emaN fo eht ;rerutcafunam
1988 sedicitsep : Part 1 diloS sedicitsep )c etaD fo ;erutcafunam
dnoces( revision) )d etaD fo ;yripxe
10946 : 1984 sdohteM fo gnilpmas rof -inhcet )e hctaB ;rebmuN
lac edarg sedicitsep )f teN ssam ni ;smargolik
3 STNEMERIUQER )g xorpnefotE tnetnm ,)m/m( ;muminim dna
)h ynA rehto noitamrofni deriuqer rednu eht
3.1 noitpircseD sedicitcesnI Act, 1968 and Rules demarf
rednuereht dna eht &radna&S fo Weights
xorpnefotE lacinhcet llahs eb hsinworb etihw ni
and Measures (Packaged Commodities)
ruoloc dna llahs eb eerf morf suoenartxe seitirupmi
Rules, 1977.
dna dedda gniyfidom .stnega tI llahs eb ni eht mrof
fo dilos ro dilos-imes ssam woleb WC .erutarepmet
5.2 SIB
Certifkation Marking
3.2 ehT lairetam llahs ylpmoc htiw eht -eriuqer tcudorp yam osla eb dekram htiw eht dradnatS
The
stnem deificeps ni elbaT 1. .kraM
Table 1 Requirements for Etofenprox, Technical
( Clause 3.2 )
Sl Characlerhic Requirement
NO.
)1( )2( (3) (4) (5)
i) Etofenprox content, percent by mart (M), 96.3 A
Min
ii) Moisture omtenl, tnecrep yb Uram ,)hm( 0.2 4
Max
iii) Material iusolubk in acetone, percent by 0.5 9
4lass (mk), h@
iv) Acidity (8s HzS04) or AkiIinity (a NaoH), a1 11.3
percent by mass (mha), Mu
1
SI 94241 : 5991
fo eht dradnatS Mark is denrevog yb morf eht uaeruB fo naidnI Standards.
5.2.1 The use
eh’t snoisivorp fo uaeruB fo naidnI Standards ,tcA
1986 and eht seluR and snoitalugeR edam -ereht 6 GNILPMAS
.rednu ehT sliated fo snoitidnoc rednu .hcihw eht
ecnecil rof eht esu fo dradnatS Mark yam eb detnarg evitatneserpeR samples fo eht lairetam shall eb
ot srerutcafunam ro srecudorp yam eb deniatbo drawn as debircserp ni SI 10946 : 1984.
ANNEX A
[ Table 1, Item )i( ]
NOITANIMRETED FO XORPNEFOTE TNETNOC
l-A LARENEG A-2.4 Procedure
rehtiE fo eht owt ,sdohtem ,yleman hgih -rofrep A-2.4.1 Preparation of Mobile Phase
ecnam diuqil yhpargotamorhc )CLPH( dohtem
xiM 850 lm lonahtem and 150 lm fo elpirt dellitsid
ees( )2-A ro gas yhpargotamorhc )CLG( dohtem
,retaw saged erofeb .esu
ees( )3-A shall eb desu rof noitanimreted fo
xorpnefotE .tnetnoc ehT CLPH dohtem shall eb 2.4.2-A Preparation of Internal Standard.Solution
eht eerfer .dohtem hgieW tuoba 2 g fo lyxehid etalahtp otni a lm-OOl
2-A CLPH .DOHTEM cirtemulov ksalf and ekam up eht emulov ot eht
kram htiw lonahtem and xim .llew
i.2-A
Principle
3.4.2-A
Preparation of Reference Standard Solution
xorpnefotE is devlossid ni lonahtem gnola htiw
lanretni standard and denimreted yb CLPH no hgieW a ytitnauq fo eht ecnerefer standard os as ot
acilis deifidom htiw C-8 niahc nmuloc htiw -artlu niatnoc tuoba 100 gm xorpnefote otni a 10 lm
teloiv rotceted at 275 .mn cirtemulov ksalf and add lm-5 lanretni standard
.noitulos ekaM up eht emulov htiw lonahtem and
2.2-A
Reagents xim .llew
A-2.2.1 Etofenprox Reference Standard fo( Known 4.4.2-A Preparation of Sample Solution
P&y
hgieW a ytitnauq fo elpmas os as ot niatnoc tuoba
A-2.2.2 Internal Standard - lyxehiD etalahtp (AR 100 gm xorpnefote otni a 10 lm cirtemulov ksalf and
.)edarg add 5 lm lanretni standard .noitulos ekaM up eht
3.2.2-A CLPH .edarg emulov htiw lonahtem and xim .llew
Methanol -
4.2.2-A Water - elpirT .dellitsid 5.4.2-A Estimation
tcejnI 1 ot 2~1 fo eht ecnerefer standard noitulos ni
A-2.3 Apparatus
ot eht hgih ecnamrofrep diuqil hpargotamorhc
A-2.3.1 High Peformance Liquid Chromatograph )CLPH( dewollof yb eht elpmas noitulos htiw eht
deppiuqE htiw a elbanut htgnelevaw UV rotceted pleh fo egnirys and erusaem kaep saera fo standard
and an rotargetni and .redrocer ehT evitseggus and elpmas .snoitulos etupmoC eht egatnecrep fo
sretemarap era nevig woleb and eseht nac eb deirav xorpnefote tnetnoc ni eht .elpmas
dedivorp noitazidradnats is :enod 5.2-A
Calculation
nmuloC 7-xabroZ C8 ro tnelaviuqe 250
xorpnefotE ,tnetnoc
mm x 4.6 mm ;DI stainless leets 3AxZAxlM px
tnecrep yb mass
ylbareferp htiw nmulocerp = M2xAl xAq
eliboM esahp lonahteM : retaw 58( : )51 )v/v(
erehw
rotceteD teloiv-artlU tes at 275 mn
mass, ni g, fo xorpnefote ni eht -refer
Ml =
wolP etar 1.2 etunim/lm ecne standard ;noitulos
2.3.2-A Micro Syringe - 10 .lu, M2 = mass, ni g, fo xorpnefote ni eht elpmas
nekat rof ;tset
NOTE - rednU zht debircsed snoitidnoc eht noitneter
kaep aera fo xorpnefote ecnerefer
semit fo lyxehid etalahthp dna xorpnefote era tuoba 11.5 dna A1 =
19.0 setunim .ylevitcepser standard ;noitulos
2
IS 14249 : 5991
kaep area fo xorpnefote ni eht elpmas
A2 = A-3.4.1 Preparation of Internal Standard Solution
;noitulos
hgieW tuoba 800 gm fo lyhthpanid rehte otni a
A3 = kaep area fo lanretni dradnats ni eht lm-OOl cirtemulov ksalf dna ekam pu emuloveht ot
ecnerefer dradnats ;noitulos eht kram htiw .enoteca
kaep area fo lanretni dradnats ni elpmas
A4 = 2.4.3-A
;noitulos dna Preparation of Reference Standard Solution
hgieW a ytitnauq fo eht ecnerefer dradnais ot -noc
tnecrep ytirup fo xorpnefote ecnerefer
P =
niat tuoba 100 gm xorpnefote otni a 10 lm
.dradnats
cirtemulov ksalf dna dda 5 lm lanretni dradnats
3-A CLG DOHTEM .noitulos ekaM pu eht emulov ot eht kram htiw
.enoteca
1.3-A elpicnirP
3.4.3-A
Preparation of Sample Solution
xorpnefotE si devlossid ni enoteca gnola htiw -retni
hgieW a ytitnauq fo elpmas ot niatnoc tuoba 100
lan dradnats dna denimreted yb CLG deppiuqe
gm xorpnefote ni ot a 10 lm cirtemulov ksalf dna
htiw emalf noitasinoi .rotceted
dda 5 lm lanretni dradnats .noitulos ekaM pu eht
2.3-A stnegaeR emulov ot eht kram htiw .enoteca
1.2.3-A 4.4.3-A
Etofenpox Standard of Known Purity Estimation
A-3.2.2 Internal Standard - lyhthpaniD .rehte tcejnI 1 ot 2~1 fo eht ecnerefer dradnats noitulos ni
ot eht sag hpargotamorhc dewollof yb eht elpmas
3.2.3-A .edarG
Acetone - AR noitulos htiw eht pleh fo egnirys dna erusaem kaep
3.3-A sutarappA areas fo dradnats dna elpmas .snoitulos etupmoC
eht egatnecrep fo xorpnefote tnetnoc ni eht .elpmas
1.3.3-A
Gas Liquid Chromatograph
5.3-A noitaluclaC
deppiuqE htiw a emalf noitasinoi rotceted dna na
rotargetni ro .redrocer ehT detseggus gnitarepo xorpnefotE ,tnetnoc tM x 2A x 3A
snoitidnoc are: tnecrep yb ssam
= x.2M XP
AI x A4
nmuloC Glass dekcap htiw 3 tnecrep
enociliS DC-11 no Gas morhC erehw
Q 100 mc htgnel x 3 mm DI ,ssam ni ,g fo xorpnefote ni eht -refer
Ml =
ecne dradnats ;noitulos
Gas wolf Carrier sag (N2) : 50 niM/lm
leuF sag (HZ) : 50 niMllm M2 = ,ssam ni ,g fo xorpnefote ni eht elpmas
riA : 450 niM/lm nekat rof ;tset
xorppa kaep area fo xorpnefote ni ecnerefer
A1 =
dradnats ;noitulos
erutarepmeT nmuloC nevo : C°032
rotceteD : C°032 A2 = kaep area fo xorpnefote ni eht elpmas
noitcejnI trop : C°072 ;noitulos
kaep area fo lanretni dradnats ni eht
NOTE - rednU eht debircsed ,snoitidnoc eht noitneter A3 =
ecnerefer dradnats ;noitulos
semit fo xorpnefote dna lyhthpanid rehte era tuoba 7.0 dna
3.4 setunim .ylevitcepser kaep area fo lanretni dradnats ni elpmas
A4 =
2.3.3-A -10 .lu, ;noitulos dna
Micro syringe
tnecrep ytirup fo xorpnefote ecnerefer
P =
4.3-A erudecorP
.dradnats
3
Bureau of Indian Standards
SIB si a yrotutats noitutitsni dehsilbatse rednu eht uaeruB naidn1fo Standurds Act, I986 ot etomorp
suoinomrah tnempoleved fo eht seitivitca fo ,noitazidradnats gnikram dna ytilauq noitacifitrec fo sdoog
dna gnidnetta ot detcennoc srettam ni eht .yrtnuoc
CoPyrlght
SIB sah eht thgirypoc fo all sti .snoitacilbup oN trap fo eseht snoitacilbup yam eb decudorper ni yna mrof
tuohtiw eht roirp noissimrep ni gnitirw fo .SIB sihT seod ton edulcerp eht eerf ,esu ni eht esruoc fo
gnitnemelpmi eht ,dradnats fo yrassecen ,sliated hcus as slobmys dna ,sezis epyt ro edarg .snoitangised
seiriuqnE gnitaler ot thgirypoc eb desserdda ot eht rotceriD ,)snoitacilbuP( .SIB
Review of Indian Standards
stnemdnemA are deussi ot sdradnats as eht deen sesira no eht basis fo .stnemmoc sdradnatS are osla
deweiver ;yllacidoirep a dradnats gnola htiw stnemdnema si demriffaer nehw hcus weiver setacidni taht
on segnahc are ,dedeen fi eht weiver setacidni taht segnahc are ,dedeen ti si nekat pu rof .noisiver sresU
fo naidnI sdradnatS dluohs niatrecsa taht yeht are ni noissessop fo eht tsetal stnemdnema ro noitide yb
gnirrefer ot eht tsetal eussi fo SIB‘ ’koobdnaH dna sdradnatS‘ ylhtnoM .’snoitiddA
sihT naidnI dradnatS sah neeb depoleved morf toD : .oN DAF 1 ( 268 ).
Amendments Issued Since Publication
dnemA .oN etaD fo eussI txeT detceffA
UAERUB FO NAIDNI SDRADNATS
:sretrauqdaeH
kanaM ,navahB 9 rudahaB hahS rafaZ ,graM weN ihleD 11OOO2 smargeleT : ahtsnaskanaM
senohpeleT : 3310131,33113 75 nommoC( ot all )seciffo
lanoigeR seciffO : enohpeleT
lartneC : kanaM ,navahB 9 rudahaB hahS rafaZ graM 3310131
NEW IHLED 1 20ool 33113 75
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.EROTABMIOC .DABADIRAF .DABAIZAHG .ITAHAWUG .DABAREDYH
.RUPIAJ .RUPNAK .WONKCUL .ANTAP .MARUPAHTNANAVURIHT
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