Anticorrosive Nanomaterials: Future Perspectives

313 Pages·2022·7.992 MB·English

by  Verma C., Hussain C.M., Ebenso E. (ed.)

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Nanoscience & Nanotechnology Series
Anticorrosive
Nanomaterials
Future Perspectives
Edited by Chandrabhan Verma,
Chaudhery Mustansar Hussain and Eno E. Ebenso
Anticorrosive Nanomaterials
Future Perspectives
Nanoscience & Nanotechnology Series
Editor-in-chief:
~
Nguyˆen T. K. Thanh, University College London, UK
Series editors:
Gabriel Caruntu, Central Michigan University, USA
ShinyaMaenosono,JapanAdvancedInstituteofScienceandTechnology,Japan
Neerish Revaprasadu, University of Zululand, South Africa
Titles in the series:
1: Nanotubes and Nanowires
2: Fullerenes: Principles and Applications
3: Nanocharacterisation
4: Atom Resolved Surface Reactions: Nanocatalysis
5:BiomimeticNanoceramicsinClinicalUse:FromMaterialstoApplications
6: Nanofluidics: Nanoscience and Nanotechnology
7: Bionanodesign: Following Nature’s Touch
8: Nano-Society: Pushing the Boundaries of Technology
9: Polymer-based Nanostructures: Medical Applications
10: Metallic and Molecular Interactions in Nanometer Layers, Pores and
Particles: New Findings at the Yoctolitre Level
11: Nanocasting: A Versatile Strategy for Creating Nanostructured
Porous Materials
12: Titanate and Titania Nanotubes: Synthesis, Properties and Applications
13: Raman Spectroscopy, Fullerenes and Nanotechnology
14: Nanotechnologies in Food
15: Unravelling Single Cell Genomics: Micro and Nanotools
16: Polymer Nanocomposites by Emulsion and Suspension
17: Phage Nanobiotechnology
18: Nanotubes and Nanowires, 2nd Edition
19: Nanostructured Catalysts: Transition Metal Oxides
20: Fullerenes: Principles and Applications, 2nd Edition
21: Biological Interactions with Surface Charge Biomaterials
22:NanoporousGold:FromanAncientTechnologytoaHigh-TechMaterial
23: Nanoparticles in Anti-Microbial Materials: Use and Characterisation
24: Manipulation of Nanoscale Materials: An Introduction to
Nanoarchitectonics
25:TowardsEfficientDesigningofSafeNanomaterials:InnovativeMerge of
Computational Approaches and Experimental Techniques
26: Polymer–Graphene Nanocomposites
27: Carbon Nanotube-Polymer Composites
28: Nanoscience for the Conservation of Works of Art
29: Polymer Nanofibers: Building Blocks for Nanotechnology
30: Artificial Cilia
31: Nanodiamond
32: Nanofabrication and its Application in Renewable Energy
33: Semiconductor Quantum Dots: Organometallic and Inorganic Synthesis
34: Soft Nanoparticles for Biomedical Applications
35: Hierarchical Nanostructures for Energy Devices
36: Microfluidics for Medical Applications
37: Nanocharacterisation, 2nd Edition
38: Thermometry at the Nanoscale: Techniques and Selected Applications
39: Nanoceramics in Clinical Use: From Materials to Applications,
2nd Edition
40: Near-infrared Nanomaterials: Preparation, Bioimaging and
Therapy Applications
41: Nanofluidics, 2nd Edition
42: Nanotechnologies in Food, 2nd Edition
43: ZnO Nanostructures: Fabrication and Applications
44: Diatom Nanotechnology: Progress and Emerging Applications
45: Nanostructured Materials for Type III Photovoltaics
46: Chemically Derived Graphene: Functionalization, Properties and
Applications
47: Graphene-based Membranes for Mass Transport Applications
48: Carbon Nanostructures for Biomedical Applications
49: Surface Chemistry of Colloidal Nanocrystals
50: Reducing Agents in Colloidal Nanoparticle Synthesis
51: Carbon Nitride Nanostructures for Sustainable Energy Production and
Environmental Remediation
52: Nanotubes and Nanowires, 3rd Edition
53: Bionanodesign: Old Forms for New Functions, 2nd Edition
54: Photothermal Nanomaterials
55: Concepts and Design of Materials Nanoarchitectonics
56: Anticorrosive Nanomaterials: Future Perspectives
How to obtain future titles on publication:
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Visit our website at www.rsc.org/books
Anticorrosive Nanomaterials
Future Perspectives
Edited by
Chandrabhan Verma
King Fahd University of Petroleum and Minerals, Saudi Arabia
Email: [email protected]
Chaudhery Mustansar Hussain
New Jersey Institute of Technology, USA
Email: [email protected]
and
Eno Ebenso
University of South Africa, South Africa
Email: [email protected]
Nanoscience&NanotechnologySeriesNo.56
PrintISBN:978-1-83916-411-8
PDFISBN:978-1-83916-625-9
EPUBISBN:978-1-83916-626-6
PrintISSN:1757-7136
ElectronicISSN:1757-7144
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rTheRoyalSocietyofChemistry2022
Allrightsreserved
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Preface
Corrosionisahighlychallenginganddamagingphenomenonandtherefore
various methods of corrosion mitigation have been developed depending
upon the nature of the metal and the environment. The use of organic
corrosion inhibitors is one of the most popular, economic and effective
methods of corrosion prevention. However, recently, nanomaterials and
nanocomposite materials have been developed as the most noble and ef-
fective alternatives to be used as corrosioninhibitors inplace of traditional
organiccorrosioninhibitors.Becauseoftheirhighsurfacearea,theyprovide
reasonably high anticorrosive activity. Nanomaterials and nanocomposites
are used as corrosion inhibitors in both aqueous and solution phases. This
book deals with the anticorrosive effect of nanomaterials and nanocompo-
sites for different metals and alloys.
The book has been divided into various chapters. Chapter 1 is about the
basic properties and anticorrosive application of various types of nanoma-
terials.Chapter2includesanintroductiontonanocompositesanddiscusses
their synthesis, characterization and application, including their use as
corrosion inhibitors. In Chapter 3, the basics of corrosion and corrosion
prevention are discussed. The various forms of corrosion and their salient
featureshavealsobeendiscussedinthischapter.Theanticorrosioneffectof
carbonnanotubes(CNTs)isdiscussedinChapter4.Thesalientpropertiesof
CNTsincorrelationwiththeircorrosioninhibitionpotentialhavealsobeen
describedinthischapter.InChapters5and6,thepropertiesandcorrosion
inhibition potential of nanocontainers and carbon dots (CDs) have been
described, respectively.
Chapters7and8areabouttheanticorrosioneffectofmetaloxidessuchas
gold, copper, iron and zinc oxides. The mechanism of corrosion inhibition
usingmetaloxideshasalsobeenpresented.Chapters9and10describethe
Nanoscience&NanotechnologySeriesNo.56
AnticorrosiveNanomaterials:FuturePerspectives
EditedbyChandrabhanVerma,ChaudheryMustansarHussainandEnoEbenso
rTheRoyalSocietyofChemistry2022
PublishedbytheRoyalSocietyofChemistry,www.rsc.org
vii
viii Preface
corrosion inhibition effectiveness of mesoporous materials and natural
fiber-based nanocomposites, respectively. A detailed description on the
anticorrosion effect of nanocomposites for steel corrosion is described in
Chapter 11. The economics and commercialization of nanomaterials and
nanocomposites as corrosion inhibitors are discussed in Chapter 12.
Overall, this book is written for scholars in academia and industry,
working in corrosion engineering, materials science and applied chem-
istry. The editors and contributors are well-known professionals, scientists
and researchers from academia and industry. We are very thankful to the
authors for their amazing and passionate efforts in the making of this
book. We give special thanks to Prof. M. A. Quraishi, who guided us
continuously in the drafting of this book. Also, special thanks to Katie
Morrey (Commissioning Editor) and Amina Headley (Editorial Assistant)
for their dedicated support and help during this project. Finally, we thank
the RSC for publishing this book.
Chandrabhan Verma
Chaudhery Mustansar Hussain
Eno E. Ebenso
Editor Biography
Chandrabhan Verma, PhD, works at the Inter-
disciplinary Research Center for Advanced
Materials,KingFahdUniversityofPetroleumand
Minerals, Dhahran 31261, Saudi Arabia. He is a
memberoftheAmericanChemicalSociety(ACS).
His research is mainly focused on the synthesis
and design of environmentally-friendly corrosion
inhibitors useful for industries. Dr. Verma is the
author of numerous research and review articles
publishedinpeer-reviewedinternationaljournals,
includingplatformsofACS,Elsevier,RoyalSociety
ofChemistry,WileyandSpringer.Dr.Vermacur-
rently edits various books for the ACS, Elsevier,
Royal Society of Chemistry and Wiley platforms. He has more than 5000 total
citations with an H-index of 40 and i-10 index of 91. Dr. Verma has received
severalnationalandinternationalawardsforhisacademicachievements.
Nanoscience&NanotechnologySeriesNo.56
AnticorrosiveNanomaterials:FuturePerspectives
EditedbyChandrabhanVerma,ChaudheryMustansarHussainandEnoEbenso
rTheRoyalSocietyofChemistry2022
PublishedbytheRoyalSocietyofChemistry,www.rsc.org
ix
x EditorBiography
ChaudheryMustansarHussain,PhD,isanadjunct
professor, academic advisor, and director of che-
mistryandEVSCLabsintheDepartmentofChe-
mistry&EnvironmentalSciencesattheNewJersey
InstituteofTechnology(NJIT),Newark,NewJersey,
USA.Hisresearchisfocusedontheapplicationsof
nanotechnologyandadvancedmaterials,environ-
mental management, analytical chemistry and
othervariousindustries.Dr.Hussainistheauthor
of numerous papers in peer-reviewed journals as
wellasaprolificauthorandeditorofaround100
books,includingscientificmonographsandhand-
booksinhisresearchareas.Hehaspublishedwith
Elsevier,RoyalSocietyofChemistry,JohnWiley&Sons,CRCPressandSpringer.
EnoE.Ebenso,PhD,isafullProfessorofPhysical
Chemistry in the Department of Chemistry at
theNorth-WestUniversityandActingDirectorof
Material Science Innovation and Modeling
ResearchFocusAreainSouthAfrica.Hisresearch
interests span through physical chemistry (elec-
trochemistry, kinetics, adsorption, thermo-
dynamicsofcorrosion)andextensiveresearchon
corrosion inhibition in different media using
electrochemical, gravimetric, gasometrical and
thermometric methods; synergistic and an-
tagonistic studies. Plant extracts, exudate gums,
polymers, ionic liquids, synthetic organic and
inorganiccompoundshavebeeninvestigatedasinhibitors.Hehaspublished
extensivelyinlocalandinternationalpeer-reviewedjournalsofwidereadership
withover300publications(articlesinnewspapers,plenary/invitedlecturesand
conferenceproceedingsnotincluded).Hehaspublishedwidelyandextensively
intheareaofcorrosioninhibitionchemistryandcurrentlyhasanH-Indexof
65 and over 10000 total citations from the Scopus Search Engine of Elsevier
Science since 1996. According to the Elsevier SciVal Insights Report
(2010–2015), he has a citation impact 10% above the world average, is the
secondmostprolificauthorinthefieldofcorrosioninhibitionworldwideand
hispublicationsarethefifthmostdownloadedgloballyinthefieldofcorrosion
inhibition. His Google Scholar Citations since 2013 are over 8000 with
an H-index of 67 and i10-index of 216. His RESEARCHERID account shows
anH-indexof44withtotalcitationsof5779andaveragecitationperarticleof
24.78. Heis a member ofthe Chemical Society of Nigeria (MCSN), American
ChemicalSociety(MACS),NewYorkAcademyofSciences,NigerianCorrosion
Society,SocietyfortheAdvancementofElectrochemicalScience&Technology,
InternationalSocietyofElectrochemistry(ISE),SouthAfricanChemicalInsti-
tute,SouthAfricanCouncilforNaturalScientificProfessionsandmanyother
scientific professional bodies. He is also a Fellow of the Royal Society of
Chemistry(UK)andamemberofAcademyofScienceofSouthAfrica(ASSAf).