Table Of ContentGmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
Gmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
Gmelin Handbuch der Anorganischen Chemie
Achte, voLLig neu bearbeitete Auflage
PREPARED Gmelin-Institut fur Anorganische Chemie
AND ISSUED BY der Max-Planck-GeseLLschaft
zur F6rderung der Wissenschaften
Director: Ekkehard Fluck
FOUNDED BY Leopold Gmelin
8TH EDITION 8th Edition begun under the auspices of the
Deutsche Chemische GeseLLschaft by R. J. Meyer
CONTINUED BY E. H. E. Pietsch and A. Kotowski, and by
Margot Becke-Goehring
Springer-Verlag Berlin Heidelberg GmbH 1993
Gmelin-Institut fOr Anorganische Chemie
der Max-Planck-GeseLLschaft zur Forderung der Wissenschaften
ADVISORY BOARD
Min.-Rat Dr. H. Bechte (Bundesministerium fOr Forschung und Technologie, Bonn), Prof.
Dr. K. Dehnicke (Philipps-Universitat, Marburg), Prof. Dr. H. GrOnewald (Bayer AG, Lever
kusen). Prof. Dr. H. Harnisch, Chairman (Hoechst AG, Frankfurt/Main-Hochst), Prof. Dr.
H. Noth (Ludwig-Maximilians-Universitat, MOnchen), Prof. Dr. H. Offermanns (Degussa AG,
Frankfurt/Main), Prof. Dr. A. Simon (Max-Planck-Institut fOr Festkorperforschung, Stuttgart),
Prof. Dr. Dr. h.c. muLt. G. Wilke (Max-PLanck-lnstitut fOr Kohlenforschung, MOlheim/Ruhr),
Prof. Dr. H. F. Zacher (Prasident der Max-Planck-GeseLLschaft, MOnchen)
DIRECTOR
Prof. Dr. Dr. h.c. Ekkehard Fluck
CORRESPONDENT MEMBERS OF THE SCIENTIFIC STAFF Dr. U. KrOerke, Dr. R. H. MiLLer,
Dr. A. R. Pebler, Dr. K. Rumpf
EMERITUS MEMBER OF THE INSTITUTE Prof. Dr. Dr. E.h. Margot Becke
CORRESPONDENT MEMBERS OF THE INSTITUTE Prof. Dr. Dr. h.c. Hans Bock,
Prof. Dr. Dr. ALois Haas, Sc. D. (Cantab.)
GMELIN HANDBOOK
Dr. J. von Jouanne
Dr. L. Berg, Dr. H. Bergmann, Dr. J. Faust, J. FOsseL, Dr. H. Katscher, Dr. R. Keirn, Dipl.-Phys.
D. KoscheL, Dr. A. Kubny, Dr. P. MerLet, Dr. M. Mirbach, Prof. Dr. W. Petz, Dr. F. A. SchrOder,
Dr. A. SLawisch, Dr. W. Topper
Dr. R. ALbrecht, Dr. G. Bar, D. BartheL, Dr. N. Baumann, Dr. K. Behrends, Dr. W. Behrendt,
D. Benzaid, Dr. R. Bohrer, K. D. Bonn, Dipl.-Chem. U. BoBLet, Dr. U. Busch, A.-K. Castro,
Dipl.-Ing. V. A. Chavizon, E. CLoos, A. Dittmar, Dipl.-Geol. R. Ditz, R. Dowideit, Dr. H.-J.
Fachmann, B. Fischer, Dr. D. Fischer, Dipl.-Ing. N. Gagel, Dr. K. Greiner, Dipl.-Bibl.
W. Grieser, Dr. R. HauboLd, Dipl.-Min. H. Hein, H.-P. Hente, H. W. HeroLd, U. Hettwer, G.
HoeLL, Dr. G. Hones, Dr. W. Hoffmann, G. Horndasch, Dr. W. HuisL, Dr. M. IrmLer, B. Jaeger,
Dr. R. Jotter, Dipl.-Chem. P. Kampf, Dr. B. KaLbskopf, H.-G. Karrenberg, Dipl.-Phys. H.
KeLLer-Rudek, Dipl.-Chem. C. KoeppeL, Dr. M. Korfer, R. KoLb, Dr. M. Kotowski, E. Kranz,
E. Krawczyk, Dipl.-Chem. I. KreuzbichLer, Dr. V. Kruppa, Dr. W. Kurtz, M. Langer, Dr. B.
LedOc, H. Mathis, E. Meinhard, M. MeBer, C. Metz, K. Meyer, E. MLitzke, Dipl.-Chem. B.
Mohsin, Dr. U. Neu-Becker, K. Noring, Dipl.-Min. U. NohL, Dr. U. Ohms-Bredemann, Dr.
H. PscheidL, Dipl.-Phys. H.-J. Richter-Ditten, E. RudoLph, G. RudoLph, Dr. B. Sarbas, Dr.
H. Schafer, Dr. R. Schemm, Dr. D. Schioberg, V. Schlicht, Dipl.-Chem. D. Schneider, E.
Schneider, A. SchwarzeL, Dr. B. Schwager, R. Simeone, Dr. F. Stein, Dr. C. Strametz, Dr.
G. Swoboda, Dr. D. Tille, A. Tuttas, Dipl.-Phys. J. Wagner, R. Wagner, M. Walter, Dr. E.
Warkentin, Dr. C. Weber, Dr. A. WieteLmann, Dr. M. Winter, Dr. B. Wobke, K. WoLff
GMELIN ONLINE
Dr. R. DepLanque
Dr. P. Kuhn, Dr. G. OLbrich
Dr. R. Baier, Dr. B. Becker, Dipl.-Chem. E. Best, Dr. H.-U. Bohmer, Dipl.-Phys. R. Bost,
Dr. A. BrandL, Dr. R. Braun, Dr. T. Buck, Dipl.-Chem. R. Durban, R. Hanz, Dipl.-Phys. C.
Heinrich-SterzeL, S. KaLweLLis-Mohn, Dr. A. Kirchhoff, Dipl.-Chem. H. KotteLwesch, Dr. M.
Kunz, Dr. L. Leichner, Dipl.-Chem. R. Maass, Dr. K. MOLLer, Dr. A. NebeL, Dipl.-Chem.
R. NohL, Dr. M. NohLen, H. Reinhardt, Dr. B. Rempfer, Dipl.-Ing. H. Vanecek
Organometallic Compounds in the Gmelin Handbook
The following listing indicates in which voLumes these compounds are discussed or are
referred to:
Ag Silber 85 (1975)
Au OrganogoLd Compounds (1980)
8e OrganoberyLLium Compounds 1 (1987)
8i 8ismut-Organische Verbindungen (1977)
Co KobaLt-Organische Verbindungen 1, 2 (1973), KobaLt Erg.-8d. A (1961),81 (1963),
82(1964)
Cr Chrom-Organische Verbindungen (1971)
Cu Organocopper Compounds 1 (1985), 2 (1983), 3 (1986), 4 (1987), Index (1987)
Fe Eisen-Organische Verbindungen A 1 (1974), A 2 (1977), A 3 (1978), A 4 (1980), A 5
(1981), A 6 (1977), A 7 (1980), Organoiron Compounds A 8 (1986), A 9 (1989), A 10
(1991), Eisen-Organische Verbindungen 81 (partly in English; 1976), Organoiron
Compounds 82 (1978), Eisen-Organische Verbindungen 83 (partly in English;
1979), 84, 85 (1978), Organoiron Compounds 86, 87 (1981), 88, 89 (1985), 810
(1986), 811 (1983), 812 (1984), 813 (1988), 814, 815 (1989), 816a, 816b, 817
(1990), 818 (1991), 819 (1992), Eisen-Organische Verbindungen C 1, C 2 (1979),
Organoiron Compounds C 3 (1980), C 4, C 5 (1981), C 6a (1991), C 6b (1992), C 7
(1985), and Eisen 8 (1929-1932)
Ga OrganogaLLium Compounds 1 (1986)
Ge Organogermanium Compounds 1 (1988), 2 (1989), 3 (1990), 5 (1993)
HI Organohalnium Compounds (1973)
In Organoindium Compounds 1 (1991)
Mo OrganomoLybdenum Compounds 5 (1992), 6 (1990), 7 (1991), 8 (1992), 9 (1993)
Nb Niob 84(1973)
Ni NickeL-Organische Verbindungen 1 (1975), 2 (1974), Register (1975), NickeL 83
(1966), and C 1 (1968), C 2 (1969)
Np, Pu Transurane C (partly in English; 1972)
Os Organoosmium Compounds A 1 (1992), 86 (1993) present volume
Pb OrganoLead Compounds 1 (1987), 2 (1990), 3 (1992)
Po PoLonium Main VoLume (1941)
Pt PLatin C (1939) and D (1957)
Re Organorhenium 1, 2 (1989), 3 (1992)
Ru Ruthenium Erg.-8d. (1970)
Sb Organoantimony Compounds 1, 2 (1981), 3 (1982), 4 (1986), 5 (1990)
Sc, Y, Rare Earth ELements D 6 (1983)
La to Lu
Sn Zinn-Organische Verbindungen 1, 2 (1975), 3, 4 (1976), 5 (1978), 6 (1979), Organotin
Compounds 7 (1980), 8 (1981), 9 (1982), 10 (1983), 11 (1984), 12 (1985), 13 (1986),
14 (1987),15,16 (1988),17 (1989),18 (1990),19 (1991), 20 (1993)
Ta TantaL 8 2 (1971)
Ti Titan-Organische Verbindungen 1 (1977), 2 (1980), Organotitanium Compounds
3 (1984), 4 and Register (1984), 5 (1990)
U Uranium Suppl. Vol. E 2 (1980)
V Vanadium-Organische Verbindungen (1971), Vanadium 8 (1967)
Zr Organozirconium Compounds (1973)
Gmelin Handbook of Inorganic
and Organometallic Chemistry
8th Edition
Os
Organoosmium
Compounds
Part 86
With 95 illustrations
AUTHOR Kerstin Behrends
EDITOR Cornelia Weber
CHIEF EDITOR Johannes FOsse!
Springer-Verlag Berlin Heidelberg GmbH 1993
LITERATURE CLOSING DATE: END OF 1992
IN MANY CASES MORE RECENT DATA HAVE BEEN CONSIDERED
Library of Congress Catalog Card Number: Agr 25-1383
ISBN 978-3-662-07538-8 ISBN 978-3-662-07536-4 (eBook)
DOI 10.1007/978-3-662-07536-4
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fee is payabLe to .. VerwertungsgeseLLschaft Wort", Munich.
© by Springer-Verlag Berlin Heidelberg 1993
Originally published by Springer-Verlag Berlin Heidelberg New York in 1993.
Solicover reprint of the hardcover 8th edition 1993
The use of registered names, trademarks, etc., in this publication does not imply, even in the absence of a specific statement,
that such names are exempt from the relevant protective laws and regulations and therefore free for general use.
Preface
The present volume, "Organoosmium Compounds" 8 6, systematically covers the litera
ture through 1992, including many later references.
This volume is the first published of Series 8. This series is devoted to compounds
containing two or more osmium atoms.
The volume forms a unit with" Organoosmium Compounds" 8 5 (in preparation). 80th
volumes deal with trinuclear compounds with ligands other than CO which are bonded
to Os by one carbon atom ("1L ligands "), regardless of whether the ligand is additionally
coordinated to Os by heteroatoms. Generally CO groups are additional ligands. As is usual
in the organometallic Gmelin series, the term "trinuclear" means three osmium atoms
in the molecule without regard to any additional metals that may be present.
The content and the subdivision of both volumes are described on p. 1. Volume 85
will deal with homometallic compounds in which the bonding C atom of the leading 1L
ligand is bonded to Os by one non-bridging Os-C bond. The first part of the present volume,
86, is devoted to homometallic compounds in which the bonding C atom of the 1L ligand
bridges two or three Os atoms. A second part deals with all heterometallic compounds
with 1L ligands other than CO.
An Empirical Formula Index and a Ligand Formula Index for both volumes 8 5 and
86 will be included in volume 8 5.
For abbreviations and dimensions used throughout this volume, see p. X.
Frankfurt am Main, October 1993 Johannes FOssel
Remarks on Abbreviations and Units
Most compounds in this volume are presented in tables. For the sake of conciseness,
some abbreviations are used and some dimensions are omitted in the tables. This necessi
tates the following clarification.
Formulas. For conciseness or for better comparison of associated compounds, labeling
can deviate from IUPAC numbering. Geometric isomers are designated according to the
IUPAC rules. Structural labels are missing when authors fail to report structural details.
Abbreviations used with temperatures are m.p. for melting point, b.p. for boiling point,
sub!. for sublimation temperature, dec. for decomposition.
Solvents or the physical state are given in parentheses immediately after the spectral
symbol if reported.
Preparations and reactions were generally carried out under an inert-gas atmosphere,
whereas workup was mostly done in air. The products were usually purified by preparative
thin-layer or column chromatography on silical gel plates or silica gel filled columns, if
not otherwise stated.
Nuclear magnetic resonance is abbreviated as NMR. Noise decoupling (if mentioned
by the authors) is indicated by braces { }. Chemical shifts are given as 8 values in ppm
with the positive sign for downfield shifts; differing signs given by authors are corrected
if possible from the given information. Reference substances are Si(CH3)4 for 1H and 13C NMR,
BF3· O(C2Hs)2 for 11B NMR, CFCl3 for 19F NMR, and H3P04 for 31p NMR, if not stated otherwise.
Multiplicities of the signals are abbreviated as s, d, t, q (singlet to quartet), quint, sext,
sept (quintet to septet), and m (multiplet); terms like dd (double doublet), s's (singlets),
and pt (pseudo triplet) are also used. Assignments referring to labeled structures are given
in the forms such as H-3,5 or C-4. Coupling constants nJ in Hz are given as J (A, B) or
as J (1,3) referring to labeled structural formulas; n is the number of bonds between the
coupled nuclei.
IR (infrared) and Raman bands are given in cm -1; in the band assignments the symbols
v, 8, g, 1:, X' and y (for stretching, deformation, rocking, twisting, wagging, and out-of-plane
bending vibrations) are omitted if not necessary; FT means Fourier Transformations, asym
and sym mean asymmetric and symmetric.
Mass spectral data are given as the most important ions or the m/e values followed
by the relative intensities in parentheses. EI means electron impact, FAB means fast atom
bombardment, and FD means field desorption. The molecular ion is abbreviated with [M]+'
Further abbreviations:
conc. concentrated c cylco
Dc calculated density C-CSH11 cyclohexyl
Dm measured density i-C3Hy CH(CH3)2
THF tetrahyd rofu ran t-C4H9 C(CH3)3
TLC preparative thin-layer chromatography
